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Ch21. Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions Nucleophilic Acyl Substitution Reactions of Acid Halides, Acid Anhydrides - Hydrolysis: Conversion into Carboxylic Acids RCOCI + H₂O RCO₂H + HCI - Conversion to Esters RCOCI + R'OH → RCO₂R' + HCI obs H₂O - Reduction (hydride attack, LiAIH4): Conversion into Alcohols (final product) CI 1) LIAIH4 2) H - Reaction with Grignard reagents, R-MgBr (1 equv. to ketone, or excess to alcohol) Reactions of Esters - Hydrolysis: Conversion of Esters into Carboxylic Acids by Aqueous Base (mechanism!) - Hydrolysis: Conversion of Esters into Carboxylic Acids by Aqueous Acid (mechanism!) NaOH, H₂O HCI, H₂O (A) (B)

Ch21. Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions Nucleophilic Acyl Substitution Reactions of Acid Halides, Acid Anhydrides - Hydrolysis: Conversion into Carboxylic Acids RCOCI + H₂O RCO₂H + HCI - Conversion to Esters RCOCI + R'OH → RCO₂R' + HCI obs H₂O - Reduction (hydride attack, LiAIH4): Conversion into Alcohols (final product) CI 1) LIAIH4 2) H - Reaction with Grignard reagents, R-MgBr (1 equv. to ketone, or excess to alcohol) Reactions of Esters - Hydrolysis: Conversion of Esters into Carboxylic Acids by Aqueous Base (mechanism!) - Hydrolysis: Conversion of Esters into Carboxylic Acids by Aqueous Acid (mechanism!) NaOH, H₂O HCI, H₂O (A) (B)

Chemistry
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please complete boxed reactions. Thanks. P.s. this is not graded work but a study guide.

Ch21. Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions Nucleophilic Acyl Substitution Reactions of Acid Halides, Acid Anhydrides - Hydrolysis: Conversion into Carboxylic Acids RCOCI+ H₂O → RCO₂H + HCI - Conversion to Esters RCOCI + R'OH → RCO₂R' + HCI H₂O - Reduction (hydride attack, LiAlH4): Conversion into Alcohols (final product) 1) LIAIH4 + 2) H - Reaction with Grignard reagents, R-MgBr (1 equv. to ketone, or excess to alcohol) Reactions of Esters - Hydrolysis: Conversion of Esters into Carboxylic Acids by Aqueous Base (mechanism!) - Hydrolysis: Conversion of Esters into Carboxylic Acids by Aqueous Acid (mechanism!) NaOH, H₂O HCI, H₂O (A) (B)
Transcribed Image Text:Ch21. Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions Nucleophilic Acyl Substitution Reactions of Acid Halides, Acid Anhydrides - Hydrolysis: Conversion into Carboxylic Acids RCOCI+ H₂O → RCO₂H + HCI - Conversion to Esters RCOCI + R'OH → RCO₂R' + HCI H₂O - Reduction (hydride attack, LiAlH4): Conversion into Alcohols (final product) 1) LIAIH4 + 2) H - Reaction with Grignard reagents, R-MgBr (1 equv. to ketone, or excess to alcohol) Reactions of Esters - Hydrolysis: Conversion of Esters into Carboxylic Acids by Aqueous Base (mechanism!) - Hydrolysis: Conversion of Esters into Carboxylic Acids by Aqueous Acid (mechanism!) NaOH, H₂O HCI, H₂O (A) (B)
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