CH₂ Proton Label a b с d e Chemical shift (ppm) Click or tap Click or tap Click or tap Type response here Explain the multiplicity for Ha and Hb. Type response here Click or tap Click or tap Relative Integration Click or tap Click or tap Click or tap Click or tap Click or tap Multiplicity (predicted) Click or tap here Click or tap here Click or tap here Click or tap here Click or tap here There are two doublets in the aromatic region. Assign these signals to the corresponding protons and justify your choice. Hint: Draw at least one representative resonance structure for the compound using each of the substituents separately (see the question in the previous experiment for guidance), classify the substituents as either electron-donating or electron-withdrawing and decide if the adjacent protons are shielded or deshielded.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
H.
H
CH3
Proton
Label
a
b
C
d
e
Chemical shift
(ppm)
Click or tap
Click or tap
Click or tap
Click or tap
Click or tap
Relative
Integration
Click or tap
Click or tap
Click or tap
Click or tap
Click or tap
Multiplicity
(predicted)
Click or tap here
Click or tap here
Click or tap here
Click or tap here
Click or tap here
There are two doublets in the aromatic region. Assign these signals to the corresponding
protons and justify your choice. Hint: Draw at least one representative resonance
structure for the compound using each of the substituents separately (see the question in
the previous experiment for guidance), classify the substituents as either electron-donating
or electron-withdrawing and decide if the adjacent protons are shielded or deshielded.
Type response here
Explain the multiplicity for Ha and Hb.
Type response here
Transcribed Image Text:H. H CH3 Proton Label a b C d e Chemical shift (ppm) Click or tap Click or tap Click or tap Click or tap Click or tap Relative Integration Click or tap Click or tap Click or tap Click or tap Click or tap Multiplicity (predicted) Click or tap here Click or tap here Click or tap here Click or tap here Click or tap here There are two doublets in the aromatic region. Assign these signals to the corresponding protons and justify your choice. Hint: Draw at least one representative resonance structure for the compound using each of the substituents separately (see the question in the previous experiment for guidance), classify the substituents as either electron-donating or electron-withdrawing and decide if the adjacent protons are shielded or deshielded. Type response here Explain the multiplicity for Ha and Hb. Type response here
Refer to the H-NMR for the product given below. The spectrum shows signals at 1.4ppm, 4.1
ppm, 4.3 ppm, 6.6 ppm and 7.8 ppm with relative integrations of approximately 3:2:2:2:2
respectively. The small peak at 1.7 ppm can be ignored.
2
2
2
Removed by
D₂O shake
2
3
0 ppm
Given the following proton assignments for the product, fill in the table provided below:
Transcribed Image Text:Refer to the H-NMR for the product given below. The spectrum shows signals at 1.4ppm, 4.1 ppm, 4.3 ppm, 6.6 ppm and 7.8 ppm with relative integrations of approximately 3:2:2:2:2 respectively. The small peak at 1.7 ppm can be ignored. 2 2 2 Removed by D₂O shake 2 3 0 ppm Given the following proton assignments for the product, fill in the table provided below:
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