ch choice best explains why the molecules below can be distinguished by IR H Molecule A Molecule A has a peak just above 3000 cm" and Molecule B does not Molecule A has a peak for an aldehyde around 2200 cm" and Molecule B does not Molecule B has a carbonyl peak around sa cm and Molecule A does not Molecule A and Molecule B can't be easily distinguished by IR CH₂ Molecule B
Reactive Intermediates
In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reactive intermediates can be isolated.
Hydride Shift
A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carbocation to attain stability in the compound. Such structural reorganization movement is called a shift within molecules. After the shifting of carbocation over the different carbon then they form structural isomers of the previous existing molecule.
Vinylic Carbocation
A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond therefore it is sp hybridized. It is known to be a part of various reactions, for example, electrophilic addition of alkynes and solvolysis as well. It plays the role of a reactive intermediate in these reactions.
Cycloheptatrienyl Cation
It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthesized from tropine.
Stability of Vinyl Carbocation
Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.
![**Distinguishing Molecules Using Infrared (IR) Spectroscopy**
**Question:**
Which choice best explains why the molecules below can be distinguished by IR?
**Image Description:**
The image shows structural formulas of two molecules labeled Molecule A and Molecule B. Molecule A is benzaldehyde consisting of a benzene ring with an attached aldehyde group (CHO). Molecule B is acetophenone with a benzene ring attached to a ketone group (COCH₃).
**Multiple Choice Options:**
A. Molecule A has a peak just above 3000 cm⁻¹ and Molecule B does not.
B. Molecule A has a peak for an aldehyde around 2200 cm⁻¹ and Molecule B does not.
C. Molecule B has a carbonyl peak around 1750 cm⁻¹ and Molecule A does not.
D. Molecule A and Molecule B can't be easily distinguished by IR.
**Explanation:**
Infrared (IR) spectroscopy is a technique used to identify and study chemicals by measuring the absorption of infrared radiation at different frequencies. Certain functional groups within molecules absorb characteristic frequencies of infrared light, which appear as peaks in an IR spectrum.
- **Option A:** Molecule A has a peak just above 3000 cm⁻¹ due to the C-H stretching in the aldehyde group. Molecule B, which has a ketone group instead, will not have this peak.
- **Option B:** Aldehydes typically show a peak around 1725 cm⁻¹ for C=O stretching, not at 2200 cm⁻¹, so this statement is not correct.
- **Option C:** Ketones show a strong carbonyl (C=O) peak near 1715 cm⁻¹, so Molecule B will have such a peak; but Molecule A, which also contains a carbonyl group, will have overlapping peaks making option C less specific.
- **Option D:** This statement is incorrect as IR spectroscopy can distinguish the functional groups present in these molecules.
Accordingly, the correct answer is **Option A**.
This explanation helps us understand how to use IR spectroscopy to differentiate between molecules with similar but distinct functional groups based on their unique absorption peaks.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F15ddb6cd-6983-4657-9770-05e88534b1be%2F5c5517af-968b-4a99-96ce-f189184b2cb6%2Fvqyz23g_processed.jpeg&w=3840&q=75)
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