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CH₂-CH₂-CH₂-Br CH₂-CEC H₂ Lindlar catalyst B

CH₂-CH₂-CH₂-Br CH₂-CEC H₂ Lindlar catalyst B

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question 12: What is the final organic * product of the synthesis scheme in Figure 12? [Give a SMILES notation.] Your answer Figure 12 CH3-CH₂-CH₂-Br CH-C=c° A H₂ Lindlar catalyst B
Transcribed Image Text:Question 12: What is the final organic * product of the synthesis scheme in Figure 12? [Give a SMILES notation.] Your answer Figure 12 CH3-CH₂-CH₂-Br CH-C=c° A H₂ Lindlar catalyst B
Expert Solution
Step 1

Conditions of bimolecular substitution (SN2) reactions-

  1. Primary carbon favors faster (SN2) reaction
  2. The reagent should be a good nucleophile.
  3. Order of (SN2) rates follows primary > secondary > tertiary. 

Similarly, conditions for SN1 reactions-

  1. Tertiary carbon favors faster (SN1) reaction
  2. The reagent should  not be a good nucleophile.
  3. Order of (SN1) rates follows primary <secondary< tertiary
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