cc. but-3-en-2-one + CH3MGBR The Nucleophile is Resonance System Option 1: Only the Nu created from RMgBr, NaBH, or LIAIH, sticks :0 8- R- -CH: Option 2: All other Nu end up here eventually 1 (Preferred) NUB (option 1 is react the electron-rich nucleophile with the electron- deficient carbonyl carbon) (option 2 is to react the electron-rich nucleophile with the slightly electron-deficient carbon at the end of the resonance system.) Circle the option and reason for reacting with a particular site of the carbonyl compound Option 1: RMgBr, LIAIH4, or NaBH4 Option 2: All other Nu end up sticking here 2. Take care of the negative formal charge of the oxygen in the tetrahedral complex Option 1 (Preferred): All cases except Option 2 1 (Preferred) Option 2: If there are no leaving groups, R or if the only potential leaving group is the Nu that was just added and it is not a very good leaving group (N or O). (option 1 is reform the double bond) (option 2 is add a hydrogen ion) Circle the option and reason Option 1: Always use UNLESS Option 2: There is no leaving group (there are carbons and hydrogens), OR there are only carbons and hydrogens except for the Nu that * if you reform Whats the the Double bond Reason? just added, AND it is N or O. - LeGu ing group? - Ewa/ aesome? - Shells ? -charge ?
cc. but-3-en-2-one + CH3MGBR The Nucleophile is Resonance System Option 1: Only the Nu created from RMgBr, NaBH, or LIAIH, sticks :0 8- R- -CH: Option 2: All other Nu end up here eventually 1 (Preferred) NUB (option 1 is react the electron-rich nucleophile with the electron- deficient carbonyl carbon) (option 2 is to react the electron-rich nucleophile with the slightly electron-deficient carbon at the end of the resonance system.) Circle the option and reason for reacting with a particular site of the carbonyl compound Option 1: RMgBr, LIAIH4, or NaBH4 Option 2: All other Nu end up sticking here 2. Take care of the negative formal charge of the oxygen in the tetrahedral complex Option 1 (Preferred): All cases except Option 2 1 (Preferred) Option 2: If there are no leaving groups, R or if the only potential leaving group is the Nu that was just added and it is not a very good leaving group (N or O). (option 1 is reform the double bond) (option 2 is add a hydrogen ion) Circle the option and reason Option 1: Always use UNLESS Option 2: There is no leaving group (there are carbons and hydrogens), OR there are only carbons and hydrogens except for the Nu that * if you reform Whats the the Double bond Reason? just added, AND it is N or O. - LeGu ing group? - Ewa/ aesome? - Shells ? -charge ?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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