Categorize each molecule according to its hydrogen-bonding characteristics. Drag the appropriate items to their respective bins. View Available Hint(s) Reset Help CH3CH2NH2 CH3OCH3 CH3OH CH3CH2CH3 CH2=CH2 N(CH3)3 H₂O CH3C(O)CH3 no hydrogen bonding capability can be a hydrogen bond acceptor but not a hydrogen bond donor can be a hydrogen bond acceptor and a hydrogen bond donor

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. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. < cleavage Bond A • CH3 + 26. t cleavage 2°C• +3°C• Bond C Cleavage CH3 ZC '2°C. 26. E Strongest 3°C. 2C. Gund Largest BDE weakest bond In that molecule a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest C bond Produces A Weakest Bond Most Strongest Bond Stable radical Strongest Gund produces least stable radicals b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 人 8°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. methyl radical •CH3 formed in bund A Cleavage

13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. cleavage Bond A •CH3 + 26.← Cleavage 2°C. + Bond C +3°C• CH3 2C Cleavage E 2°C. 26. weakest bond Intact molecule Strongest 3°C 20. Gund Largest argest a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. C Weakest bond A Produces Most Bond Strongest Bond Strongest Gund produces least stable radicals Weakest Stable radical b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 13°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. • CH3 methyl radical Formed in Gund A Cleavage c.…

Which of the following molecules would be the least polarizable? CH3CH2CH3 O SİH3SIH3 O CH3CH3 O SİH3SIH2SİH3 All of these are equally polarizable.

Paraphrasing .ewriting Tool Car note Pirate Ship BLACKBOARD [Review Topics] [References] Carbon-hydrogen bonds exhibit a range of different chemical reactivity that depends on molecular structure. Classify the C-H bonds at the carbons labeled a-c in the structure below. Possible classifications are: primary, secondary, & tertiary or none if there are no hydrogens at the labeled carbon. C-H bond(s) at a( C-H bond(s) at b C-H bond(s) at c Submit Answer Retry Entire Group 9 more group attempts remaining (Previous Next Save and Exit O 14 étv MacBook Air DII 30 888 F11 F12 FB F9 F10 F7 F5 * & 4 5 6 8. de Y 11 F G V B M + ||

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19. Based on molecular mass and dipole moment of the five compounds in the table below, which one should have the highest boiling point? Dipole Moment (D) Substance Molecular Mass (amu) Propane, CH3CH2CH3 Dimethyl ether, CH3OCH3 Methylchloride, CH3C1 Acetaldehyde, CH;CHO Acetonitrile, CH3CN 44 0.1 46 1.3 50 1.9 44 2.7 41 3.9 B) CH;CN E) CH3CH2CH3 C) CH3CHO A) CH3OCH3 D) CH;CI

In a sample of bonds in the position. (Note: Remember that iodine () is larger and more likely to contribute to steric strain in the molecule.) iodocyclohexane (CH), one would expect to find most of the C-I O equatorial O trigonal pyramidal O tetrahedral Oplanar O axial Question 7 The molecule aniline is pictured here. Which of the following words could be used to describe an essential feature of aniline to someone who is familiar with chemistry, but not with this molecule? O aromatic O heterocycle O non-cyclic fused-ring system O alkane NH₂

13) Identify the all vic halides Br Br CH2 CH₂ Cl 1 CI 01 MAP IJ II (5)|) ++) (^|--|) IN 1 (od 16PRO 811) Fomen