Categorize each molecule according to its hydrogen-bonding characteristics. Drag the appropriate items to their respective bins. View Available Hint(s) Reset Help CH3CH2NH2 CH3OCH3 CH3OH CH3CH2CH3 CH2=CH2 N(CH3)3 H₂O CH3C(O)CH3 no hydrogen bonding capability can be a hydrogen bond acceptor but not a hydrogen bond donor can be a hydrogen bond acceptor and a hydrogen bond donor

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. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. < cleavage Bond A • CH3 + 26. t cleavage 2°C• +3°C• Bond C Cleavage CH3 ZC '2°C. 26. E Strongest 3°C. 2C. Gund Largest BDE weakest bond In that molecule a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest C bond Produces A Weakest Bond Most Strongest Bond Stable radical Strongest Gund produces least stable radicals b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 人 8°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. methyl radical •CH3 formed in bund A Cleavage

13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. cleavage Bond A •CH3 + 26.← Cleavage 2°C. + Bond C +3°C• CH3 2C Cleavage E 2°C. 26. weakest bond Intact molecule Strongest 3°C 20. Gund Largest argest a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. C Weakest bond A Produces Most Bond Strongest Bond Strongest Gund produces least stable radicals Weakest Stable radical b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 13°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. • CH3 methyl radical Formed in Gund A Cleavage c.…

Which of the following molecules would be the least polarizable? CH3CH2CH3 O SİH3SIH3 O CH3CH3 O SİH3SIH2SİH3 All of these are equally polarizable.

The bond dissociation energy to break 2 C-C bond(s) in 1 mole of glycerol (HOCH2CH(OH)CH2OH, see image below) molecules is H -C H- Single Bond H C N H 432 411 346 N 386 305 167 459 358 201 142 C=C 602 C=0 799 Multiple C=C 835 C=0 1072 Bonds 615 494 C=N O=0 CEN 887 N=N 942 "Al vales in ka

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19. Based on molecular mass and dipole moment of the five compounds in the table below, which one should have the highest boiling point? Dipole Moment (D) Substance Molecular Mass (amu) Propane, CH3CH2CH3 Dimethyl ether, CH3OCH3 Methylchloride, CH3C1 Acetaldehyde, CH;CHO Acetonitrile, CH3CN 44 0.1 46 1.3 50 1.9 44 2.7 41 3.9 B) CH;CN E) CH3CH2CH3 C) CH3CHO A) CH3OCH3 D) CH;CI

13) Identify the all vic halides Br Br CH2 CH₂ Cl 1 CI 01 MAP IJ II (5)|) ++) (^|--|) IN 1 (od 16PRO 811) Fomen

The face indicated by the arrow in the molecule below is the: A) Re face B) Si face C) R face D) S face H₂C H3C II. O H CH3 CH 3