Calibration data for a bromide ion-selective electrode (ISE) was collected and recorded [Br¯] (M) Potential (mV) in the table. The potential of the ISE was measured against a saturated calomel 0.300 -21.8 electrode (SCE). All solutions were buffered at a pH of 7.56. A linear calibration curve can be constructed from this data as a plot of potential (in mV) vs. log [Br¯]. Determine 0.0300 36.4 the slope and y-intercept of such a plot of the calibration data given. 0.00300 96.0 0.000300 154.8 0.0000300 224.9 slope = y-intercept = Two unknown solutions were tested for [Br¯] using the same bromide ISE. The potential reading for unknown 1 was –7.6 mV, and the potential reading for unknown 2 was 198.9 mV. Using the calibration curve you constructed, determine the concentration of Br¯ in each unknown solution. unknown 1 [Br¯] = M unknown 2 [Br¯] = M } TOOLS x10

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Calibration data for a bromide ion-selective electrode (ISE) was collected and recorded
[Br¯] (M)
Potential (mV)
in the table. The potential of the ISE was measured against a saturated calomel
0.300
-21.8
electrode (SCE). All solutions were buffered at a pH of 7.56. A linear calibration curve
0.0300
36.4
can be constructed from this data as a plot of potential (in mV) vs. log [Br]. Determine
the slope and y-intercept of such a plot of the calibration data given.
0.00300
96.0
0.000300
154.8
0.0000300
224.9
slope =
у-intercept%3D
Two unknown solutions were tested for [Br] using the same bromide ISE. The potential reading for unknown 1 was -7.6 mV,
and the potential reading for unknown 2 was 198.9 mV. Using the calibration curve you constructed, determine the concentration
of Br in each unknown solution.
unknown 1 [Br¯] =
M
unknown 2 [Br¯] =
M
* TOOLS
х10
Transcribed Image Text:Calibration data for a bromide ion-selective electrode (ISE) was collected and recorded [Br¯] (M) Potential (mV) in the table. The potential of the ISE was measured against a saturated calomel 0.300 -21.8 electrode (SCE). All solutions were buffered at a pH of 7.56. A linear calibration curve 0.0300 36.4 can be constructed from this data as a plot of potential (in mV) vs. log [Br]. Determine the slope and y-intercept of such a plot of the calibration data given. 0.00300 96.0 0.000300 154.8 0.0000300 224.9 slope = у-intercept%3D Two unknown solutions were tested for [Br] using the same bromide ISE. The potential reading for unknown 1 was -7.6 mV, and the potential reading for unknown 2 was 198.9 mV. Using the calibration curve you constructed, determine the concentration of Br in each unknown solution. unknown 1 [Br¯] = M unknown 2 [Br¯] = M * TOOLS х10
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