Calculated Heats of Reaction, AH=AHf(R')+ AHf(CH) – AHF(RCD, in kJ/mol: R=n-butyl R= sec-butyl R= tert-butyl R = crotyl Based on their Calculated Heats of Reaction, list these primary, secondary, tertiary, and allylic halides in order of increasing relative rates (slowest < fastest): Why is the allylic cation (crotyl) different in stability compared to a primary cation? (One word:)
Calculated Heats of Reaction, AH=AHf(R')+ AHf(CH) – AHF(RCD, in kJ/mol: R=n-butyl R= sec-butyl R= tert-butyl R = crotyl Based on their Calculated Heats of Reaction, list these primary, secondary, tertiary, and allylic halides in order of increasing relative rates (slowest < fastest): Why is the allylic cation (crotyl) different in stability compared to a primary cation? (One word:)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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SN1
Gas Phase PM3 Energies (kJ/mol)
AHf(RCI)
AHf(R*)
AHf(CIH)
R=n-butyl
R = sec-butyl
R= tert-butyl
R= crotyl
Calculated Heats of Reaction, AHon= AHf(R")+ AH¡(CH) - AHf(RCI), in kJ/mol:
%3D
R = n-butyl
R = sec-butyl
R= tert-butyl
R= crotyl
Based on their Calculated Heats of Reaction, list these primary, secondary, tertiary,
and allylic halides in order of increasing relative rates (slowest < fastest):
Why is the allylic cation (grotvl) different in stability compared to a primary cation?
(One word:)
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