Calculate the volumes needed to create a 50 mL buffer solution with a target pH of 4.20. Use 0.10 M solutions from List E and List F. (Use HCOOH and HCOOK, and check if the work provided below is correct) HCOOH, HCOOK A CB ott = oka + log List E 0.10 M HCOOH K = 1.8 x 10-4 0.10 M CH₂COOH K₂ = 1.8 x 10-s nislg 0.10 M NH,OH K = 1.8 x 10-5 0.10 M CH,NH, K=4.4 x 10-4 [6] ↑ List F 0.10 M CH,NH,CI 0.10 M NHẠCI 0.10 M CH,COONa 0.10 M HCOOK 0.10 M HCOONa 0.10 M CH,COOK 4.20 3.74 CHOOOK] loẾU COOHJ logi

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Chapter1: Chemical Foundations
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Calculate the volumes needed to create a 50 mL buffer solution with a target pH of 4.20. Use
0.10 M solutions from List E and List F. (Use HCOOH and HCOOK, and check if the work
provided below is correct)
HCOOH, HCOOK
A
CB
он = рка+
List E
0.10 M HCOOH
K = 1.8 x 10-4
0.10 M CH₂COOH
K₁ = 1.8 x 10-5
0.10 M NH OH
K=1.8 x 10-5
0.10 M CHẠNH,
K = 4.4 x 10-4
↓
List F
0.10 M CH,NH,CI
0.10 M NHẠCI
0.10 M CH,COONa
0.10 M HCOOK
0.10 M HCOONa
0.10 M CH,COOK
4.20 3.74 +
2.88 = CHCOOK]
Снсоон]
50mL, .050L
X= vol HCOOK
050-XE VỚI HCCH
[B]
[A]
2.88=
2.56
[HOOOK]
log pнссон]
2x
(0.10M-X)/.05L
(0-10M (050-x)/05L 0.1-2x
2x
0.1-2x
2.88 0.1-2x) = 2x
x = 0.0371
0.050-x = 0.0129
371mL HCOOK
12.9m2 HcoH
Transcribed Image Text:Calculate the volumes needed to create a 50 mL buffer solution with a target pH of 4.20. Use 0.10 M solutions from List E and List F. (Use HCOOH and HCOOK, and check if the work provided below is correct) HCOOH, HCOOK A CB он = рка+ List E 0.10 M HCOOH K = 1.8 x 10-4 0.10 M CH₂COOH K₁ = 1.8 x 10-5 0.10 M NH OH K=1.8 x 10-5 0.10 M CHẠNH, K = 4.4 x 10-4 ↓ List F 0.10 M CH,NH,CI 0.10 M NHẠCI 0.10 M CH,COONa 0.10 M HCOOK 0.10 M HCOONa 0.10 M CH,COOK 4.20 3.74 + 2.88 = CHCOOK] Снсоон] 50mL, .050L X= vol HCOOK 050-XE VỚI HCCH [B] [A] 2.88= 2.56 [HOOOK] log pнссон] 2x (0.10M-X)/.05L (0-10M (050-x)/05L 0.1-2x 2x 0.1-2x 2.88 0.1-2x) = 2x x = 0.0371 0.050-x = 0.0129 371mL HCOOK 12.9m2 HcoH
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