Calculate the volume of 85 g of chlorine gas at 73 oC and 1.54 atm.

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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  1. Calculate the volume of 85 g of chlorine gas at 73 oC and 1.54 atm.
**Problem Statement:** 

Calculate the volume of 85 g of chlorine gas at 73 °C and 1.54 atm.

**Explanation:**

To solve this problem, we will use the Ideal Gas Law, which is given by the formula:

\[ PV = nRT \]

Where:
- \( P \) is the pressure (in atm),
- \( V \) is the volume (in liters),
- \( n \) is the number of moles,
- \( R \) is the ideal gas constant (0.0821 L·atm/K·mol),
- \( T \) is the temperature (in Kelvin).

**Steps:**

1. **Convert the temperature to Kelvin:**
   \[ T(K) = 73 + 273.15 = 346.15 \, K \]

2. **Calculate the number of moles of chlorine gas:**
   The molar mass of chlorine (Cl₂) is approximately 70.9 g/mol.
   \[ n = \frac{85 \, g}{70.9 \, g/mol} = 1.20 \, mol \]

3. **Use the Ideal Gas Law to find the volume:**
   \[ V = \frac{nRT}{P} \]
   \[ V = \frac{(1.20 \, mol)(0.0821 \, L·atm/K·mol)(346.15 \, K)}{1.54 \, atm} \]

4. **Calculate the volume:**
   \[ V \approx \frac{1.20 \times 0.0821 \times 346.15}{1.54} \]
   \[ V \approx 22.1 \, L \]

Thus, the volume of 85 g of chlorine gas at 73 °C and 1.54 atm is approximately **22.1 liters**.
Transcribed Image Text:**Problem Statement:** Calculate the volume of 85 g of chlorine gas at 73 °C and 1.54 atm. **Explanation:** To solve this problem, we will use the Ideal Gas Law, which is given by the formula: \[ PV = nRT \] Where: - \( P \) is the pressure (in atm), - \( V \) is the volume (in liters), - \( n \) is the number of moles, - \( R \) is the ideal gas constant (0.0821 L·atm/K·mol), - \( T \) is the temperature (in Kelvin). **Steps:** 1. **Convert the temperature to Kelvin:** \[ T(K) = 73 + 273.15 = 346.15 \, K \] 2. **Calculate the number of moles of chlorine gas:** The molar mass of chlorine (Cl₂) is approximately 70.9 g/mol. \[ n = \frac{85 \, g}{70.9 \, g/mol} = 1.20 \, mol \] 3. **Use the Ideal Gas Law to find the volume:** \[ V = \frac{nRT}{P} \] \[ V = \frac{(1.20 \, mol)(0.0821 \, L·atm/K·mol)(346.15 \, K)}{1.54 \, atm} \] 4. **Calculate the volume:** \[ V \approx \frac{1.20 \times 0.0821 \times 346.15}{1.54} \] \[ V \approx 22.1 \, L \] Thus, the volume of 85 g of chlorine gas at 73 °C and 1.54 atm is approximately **22.1 liters**.
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