Calculate the solubility of Cd,Fe(CN), in a 0.0333 Msolution of Mg(CIO,), using activities. Use the linearinterpolation of experimental data in Table 10-2 ifnecessary.2+4-Cd,Fe(CN), (s) = 2 Cd + Fe(CN),K = 3.2sp,-17х10TABLE 10-2Activity Coefficients for lons at 25°CActivity Coefficient at Indicated Tonic StrengthJonH,OLi. CH,CO0Na", 10,5. HSO,. Hco, H,PO,. HAsO,. OACOH ,F, SCN, HS, CIO,, CIO, , BrO, , 10, , Mno,K*. CI. Br.. CN". NO,. NO,, HCOO-Rb", C, TI, Ag", NH,"M, BeC. Cut, Za, Sn", Mn", Fe, Ni, Co". PhthalateS, Ba", Cl", Hg", s-Pb*, CO,, So,.COHg,", SO,", S,0,“, Cr,. HPO,A*, Fe*, C*, L*, Ce*PO., Fe(CN),Th", Z", Ce", Sa*FelCN),0.0010.0050.010.050.10.90.9670.9340.9130.850.830.60.9660.9650.9300.9070.830.820.800.4-0.450.9270.9020.770.9260.9250.350.9650.9000.810.760.30.250.9650.8990.810.750.9650.9250.8970.800.750.80.8720.7560.6900.520.480.440.60,8700.7480.6760.400.50.8690.7430.6680.460.380.360,350.450.8680.7410.6650.450.400.8670.7380.6610.440.90.7370.5400.4430.3940.240,180.40.5050.3480.3050.7260.160.0951.10.5870.2520.100.0630.50.5690.2000.0470.020Source Reprinted (odapted) with permision from J. Kielland, /. Am. Chem. Sve., 1937, 59, 1675, DOI: 10.1021/ja0128H1032. Copyright 1937American Chemical Society.Answer:

Solution: The given data is - 0.0333M solution of Mg(ClO4)2. Ksp = 3.2 x 10^-17 Calculate the…

Calculate the solubility of Cd,Fe(CN), in a 0.0333 M solution of Mg(CIO,), using activities. Use the linear interpolation of experimental data in Table 10-2 if necessary. 2+ 4- Cd,Fe(CN), (s) =2 Cd + Fe(CN), Kn = 3.2 sp -17 x 10

Calculate the solubility of Cd,Fe(CN), in a 0.0333 M solution of Mg(CIO,), using activities. Use the linear interpolation of experimental data in Table 10-2 if necessary. 2+ 4- Cd,Fe(CN), (s) =2 Cd + Fe(CN), Kn = 3.2 sp -17 x 10

Chemistry

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ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

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Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

Calculate the solubility of Cd,Fe(CN), in a 0.0333 M
solution of Mg(CIO,), using activities. Use the linear
interpolation of experimental data in Table 10-2 if
necessary.
2+
4-
Cd,Fe(CN), (s) = 2 Cd + Fe(CN),
K = 3.2
sp,
-17
х10
TABLE 10-2
Activity Coefficients for lons at 25°C
Activity Coefficient at Indicated Tonic Strength
Jon
H,O
Li. CH,CO0
Na", 10,5. HSO,. Hco, H,PO,. HAsO,. OAC
OH ,F, SCN, HS, CIO,, CIO, , BrO, , 10, , Mno,
K*. CI. Br.. CN". NO,. NO,, HCOO-
Rb", C, TI, Ag", NH,"
M, Be
C. Cut, Za, Sn", Mn", Fe, Ni, Co". Phthalate
S, Ba", Cl", Hg", s-
Pb*, CO,, So,.CO
Hg,", SO,", S,0,“, Cr,. HPO,
A*, Fe*, C*, L*, Ce*
PO., Fe(CN),
Th", Z", Ce", Sa*
FelCN),
0.001
0.005
0.01
0.05
0.1
0.9
0.967
0.934
0.913
0.85
0.83
0.6
0.966
0.965
0.930
0.907
0.83
0.82
0.80
0.4-0.45
0.927
0.902
0.77
0.926
0.925
0.35
0.965
0.900
0.81
0.76
0.3
0.25
0.965
0.899
0.81
0.75
0.965
0.925
0.897
0.80
0.75
0.8
0.872
0.756
0.690
0.52
0.48
0.44
0.6
0,870
0.748
0.676
0.40
0.5
0.869
0.743
0.668
0.46
0.38
0.36
0,35
0.45
0.868
0.741
0.665
0.45
0.40
0.867
0.738
0.661
0.44
0.9
0.737
0.540
0.443
0.394
0.24
0,18
0.4
0.505
0.348
0.305
0.726
0.16
0.095
1.1
0.587
0.252
0.10
0.063
0.5
0.569
0.200
0.047
0.020
Source Reprinted (odapted) with permision from J. Kielland, /. Am. Chem. Sve., 1937, 59, 1675, DOI: 10.1021/ja0128H1032. Copyright 1937
American Chemical Society.
Answer:

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