Calculate the relative rate of diffusion of 1H2 (molar mass 2.0 g/mol) compared with 2H2 (molar mass 4.0 g/mol) and the relative rate of diffusion of O2 (molar mass 32 g/mol) compared with O3 (molar mass 48 g/mol).

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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5 problems on gas laws, please answer ALL problems, thank you!

1. Calculate the relative rate of diffusion of 1H2 (molar mass 2.0 g/mol) compared with 2H2 (molar mass 4.0 g/mol) and the relative rate of diffusion of O2 (molar mass 32 g/mol) compared with O3 (molar mass 48 g/mol).

2. Can the speed of a given molecule in a gas double at constant temperature? Explain your answer.

3. The distribution of molecular velocities in a sample of helium is shown in the picture attached below #5. If the sample is cooled, will the distribution of velocities look more like that of H2 or of H2O? Explain your answer.

4. A 1-L sample of CO initially at STP is heated to 546 K, and its volume is increased to 2 L.

5. Under which of the following sets of conditions does a real gas behave most like an ideal gas, and for which conditions is a real gas expected to deviate from ideal behavior? Explain.

(a) high pressure, small volume

(b) high temperature, low pressure

(c) low temperature, high pressure

Хе
Kr
Ar
Ne
Не
500 1000 1500 2000 2500 3000
Speed u (m/s)
Figure 9.34 Molecular velocity is directly related to molecular mass. At a given temperature,
lighter molecules move faster on average than heavier molecules.
Fraction of molecules
Transcribed Image Text:Хе Kr Ar Ne Не 500 1000 1500 2000 2500 3000 Speed u (m/s) Figure 9.34 Molecular velocity is directly related to molecular mass. At a given temperature, lighter molecules move faster on average than heavier molecules. Fraction of molecules
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