Calculate the pH at 25 °C of a 0.20M solution of potassium butanoate (KC,H,CO,). Note that butanoic acid (HC,H,CO,) is a weak acid with a pK, of 4.82Round your answer to 1 decimal place.pH =?

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Calculate the pH at 25 °C of a 0.20M solution

Chemistry

9th Edition

ISBN:9781133611097

Author:Steven S. Zumdahl

Publisher:Steven S. Zumdahl

Chapter17: Spontaneity, Entropy, And Free Energy

Section: Chapter Questions

Problem 100CWP

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Consider an aqueous solution of HF. The molar heat of formation for aqueous HF is -320.1 kJ/mol. (a) What is the pH of a 0.100 M solution of HF at 100C? (b) Compare with the pH of a 0.100 M solution of HF at 25C.
Weak base B has a pKb of 6.78 and weak acid HA has a pKa of 5.12. a Which is the stronger base, B or A? b Which is the stronger acid, HA or BH+? c Consider the following reaction: B(aq)+HA(aq)BH+(aq)+A(aq) Based on the information about the acid/base strengths for the species in this reaction, is this reaction favored to proceed more to the right or more to the left? Why? d An aqueous solution is made in which the concentration of weak base B is one half the concentration of its acidic salt, BHCl, where BH+ is the conjugate weak add of B. Calculate the pH of the solution. e An aqueous solution is made in which the concentration of weak acid HA twice the concentration of the sodium salt of the weak acid, NaA. Calculate the pH of the solution. f Assume the conjugate pairs B/BH+ and HA/A are capable of being used as color-based end point indicators in acidbase titrations, where B is the base form indicator and BH is the acid form indicator, and HA is the acid form indicator and A is the base form indicator. Select the indicator pair that would be best to use in each of the following titrations: (1) Titration of a strong acid with a strong base. (i) B/BH+ (ii) HA/A (2) Titration of a weak base with a strong acid. (i) B/BH+ (ii) HA/A
Ionization of the first proton from H2SO4 is complete (H2SO4 is a strong acid); the acid-ionization constant for the second proton is 1.1 102. a What would be the approximate hydronium-ion concentration in 0.100 M H2SO4 if ionization of the second proton were ignored? b The ionization of the second proton must be considered for a more exact answer, however. Calculate the hydronium-ion concentration in 0.100 M H2SO4, accounting for the ionization of both protons.
The pH of a 0.20-M solution of HP is 1.92. Determine Ka far HF from these data.
For oxyacids, how does acid strength depend on a. the strength of the bond to the acidic hydrogen atom? b. the electronegativity of the element bonded to the oxygen atom that bears the acidic hydrogen? c. the number of oxygen atoms? How does the strength of a conjugate base depend on these factors? What type of solution forms when a nonmetal oxide dissolves in water? Give an example of such an oxide. What type of solution forms when a metal oxide dissolves in water? Give an example of such an oxide.
Calculate the pH at 25 °C of a 0.73 M solution of sodium propionate (NaC,H,CO,). Note that propionic acid (HC,H,CO,) is a weak acid with a pK, of 4.89 Round your answer to 1 decimal place.
Calculate the pH at 25 °C of a 0.26M solution of sodium benzoate (NaC,H,Co,). Note that benzoic acid (HC,H,CO,) is a weak acid with apK, of 4.20. Round your answer to 1 decimal place. olo 18 Ar pH
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H. | || The percent ionization of chloroacetic acid is less than that of fluoroacetic acid. :*-C-C-ö-H The percent ionizations cannot be compared without knowing the concentrations of the two acids. The structure of haloacetic acids, XCH,COOH (where X is The percent ionizations cannot be compared without knowing the pH of the solution. either F, Cl, Br, or 1), is shown above. The dissociation constants and molar masses of four haloacetic acids are listed in the table below. The percent ionization of chloroacetic acid is greater than that of fluoroacetic acid. Acid pK. K. Molar Mass(g/mol) CLEAR ALL Fluoroacetic acid 2.59 2.57 x 10–3 78.0 Chloroacetic acid 2.87 1.35 x 10–3 94.5 Bromoacetic acid 2.90 1.26 x 10-3 138.9 lodoacetic acid 3.18 6.61 × 10-4 185.9 An aqueous solution contains small but equal concentrations of both chloroacetic and fluoroacetic acids. Which statement comparing the percent ionizations of the two acids in the solution is true? エーO-
The pH of blood is 7.4. What is the ratio (to one decimal place) of bicarbonate (conjugate base) to carbonic acid (weak acid) in the blood's buffering equilibrium? Note, the K₂ of carbonic acid is 4.27 x 10-7. Write your answer this way: # to 1 Done Clear Incorrect. The ratio is 10.7 to 1, indicating that there is 10 times more bicarbonate than carbonic acid. Enter the correct answer.
What is the concentration of H3O+ in a solution that is 0.0600 M Hypochlorous acid (HClO)? What is the pH? To solve this problem: Write the acid dissociation equilibrium for HClO Set up an ICE chart ( with x = the concentration of H3O+ at equilibrium) Write the expression for Ka. Fill this in with the concentrations of H3O+, ClO- and HClO at equilibrium, in terms of x. Decide if x can be neglected. You may neglect x if the initial concentration of the HClO is greater than 100 times the Ka. You will need the value of Ka. Look it up on the chart (p 4 of packet) Solve for x Find the pH The pH of a 0.0200 M solution of an unknown acid is 2.56. What is the Ka of this acid? To solve this problem: Write the acid dissociation equilibrium for the generic aicd “HA” Set up an ICE chart ( with x = the concentration of H3O+ at equilibrium) Write the expression for Ka. Fill this in with the concentrations of H3O+, A- and HA at equilibrium, in terms of x. What is x? Can you find it…
In aqueous solution, pentanoic acid (HC,H,0,) dissociates to produce its conjugate base, the pentanoate ion (C,H,0, ), and the hydronium ion (H,0*). The solution is at a temperature of 25°C. (a) If the K, value of pentanoic acid is 1.5x10, calculate the K, value of the conjugate base. a = 4.0 (b) What are the corresponding pk, and pk, values for this conjugate acid-base pair? 4.0 pk a 4.0 pkb (c) How is pk, related to pk? a pk, ??? v pkb = pKw = 14.00 at 25°C

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