Calculate the mole fractions of SO2•H2O, HSO3- and SO3 2- in solution at a pH of 3.0, characteristic of many fogs, as well as the total concentration of S(IV) in solution for 20 ppb SO2 in the gas phase. Constants attached in table

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Calculate the mole fractions of SO2•H2O, HSO3- and SO3 2- in solution at a pH of 3.0, characteristic of many fogs, as well as the total concentration of S(IV) in solution for 20 ppb SO2 in the gas phase. Constants attached in table
Selected Henry's Law Constants and Equilibrium Constants at 298 K.
К (М)
1.0 x 1014
H (mole L1 atm1)
Equilibrium
H20 > H* + OH
CO2 + H20 €> CO2·H2O
3.4 x 10-2
CO2·H20 > H* + HCO3
4.3 x 107
HCO3 H* + CO3²-
4.7 x 10-11
SO2 + H20 → SO2·H2O
SO2·H20 > H* + HSO3
1.23
1.32 x 10-2
HSO3 → H* + SO3²-
6.42 x 10-8
NH3 + H2O > NH3·H2O
62
NH3-H20 > NH4* + OH
1.8 x 105
HNO3 + H20 A HNO3-H2O
2.1 x 105
HNO3-H20 €> H* + NO3
15.4
H2O2 + H2O > H2O2•H2O
7.45 x 104
H2O2-H20 > H* + HO2
2.5 x 10-12
O3 + H20 → O3·H2O
0.011
Transcribed Image Text:Selected Henry's Law Constants and Equilibrium Constants at 298 K. К (М) 1.0 x 1014 H (mole L1 atm1) Equilibrium H20 > H* + OH CO2 + H20 €> CO2·H2O 3.4 x 10-2 CO2·H20 > H* + HCO3 4.3 x 107 HCO3 H* + CO3²- 4.7 x 10-11 SO2 + H20 → SO2·H2O SO2·H20 > H* + HSO3 1.23 1.32 x 10-2 HSO3 → H* + SO3²- 6.42 x 10-8 NH3 + H2O > NH3·H2O 62 NH3-H20 > NH4* + OH 1.8 x 105 HNO3 + H20 A HNO3-H2O 2.1 x 105 HNO3-H20 €> H* + NO3 15.4 H2O2 + H2O > H2O2•H2O 7.45 x 104 H2O2-H20 > H* + HO2 2.5 x 10-12 O3 + H20 → O3·H2O 0.011
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