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Calculate the mole fractions of SO2•H2O, HSO3- and SO3 2- in solution at a pH of 3.0, characteristic of many fogs, as well as the total concentration of S(IV) in solution for 20 ppb SO2 in the gas phase. Constants attached in table

Calculate the mole fractions of SO2•H2O, HSO3- and SO3 2- in solution at a pH of 3.0, characteristic of many fogs, as well as the total concentration of S(IV) in solution for 20 ppb SO2 in the gas phase. Constants attached in table

Chemistry
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Calculate the mole fractions of SO2•H2O, HSO3- and SO3 2- in solution at a pH of 3.0, characteristic of many fogs, as well as the total concentration of S(IV) in solution for 20 ppb SO2 in the gas phase. Constants attached in table
Selected Henry's Law Constants and Equilibrium Constants at 298 K. К (М) 1.0 x 1014 H (mole L1 atm1) Equilibrium H20 > H* + OH CO2 + H20 €> CO2·H2O 3.4 x 10-2 CO2·H20 > H* + HCO3 4.3 x 107 HCO3 H* + CO3²- 4.7 x 10-11 SO2 + H20 → SO2·H2O SO2·H20 > H* + HSO3 1.23 1.32 x 10-2 HSO3 → H* + SO3²- 6.42 x 10-8 NH3 + H2O > NH3·H2O 62 NH3-H20 > NH4* + OH 1.8 x 105 HNO3 + H20 A HNO3-H2O 2.1 x 105 HNO3-H20 €> H* + NO3 15.4 H2O2 + H2O > H2O2•H2O 7.45 x 104 H2O2-H20 > H* + HO2 2.5 x 10-12 O3 + H20 → O3·H2O 0.011
Transcribed Image Text:Selected Henry's Law Constants and Equilibrium Constants at 298 K. К (М) 1.0 x 1014 H (mole L1 atm1) Equilibrium H20 > H* + OH CO2 + H20 €> CO2·H2O 3.4 x 10-2 CO2·H20 > H* + HCO3 4.3 x 107 HCO3 H* + CO3²- 4.7 x 10-11 SO2 + H20 → SO2·H2O SO2·H20 > H* + HSO3 1.23 1.32 x 10-2 HSO3 → H* + SO3²- 6.42 x 10-8 NH3 + H2O > NH3·H2O 62 NH3-H20 > NH4* + OH 1.8 x 105 HNO3 + H20 A HNO3-H2O 2.1 x 105 HNO3-H20 €> H* + NO3 15.4 H2O2 + H2O > H2O2•H2O 7.45 x 104 H2O2-H20 > H* + HO2 2.5 x 10-12 O3 + H20 → O3·H2O 0.011
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