Calculate the molarity of KMNO4 solution needed to titrate 50.00 mL of a saturated solution of this oxalate salt. It should take 7.50 mL of KMnO4 solution to titrate the saturated oxalate solution.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Please solve the molarity of KMnO4, step by step in neat hand writing please
**Solubility Product Constant**

**Identity of Oxalate Salt:** SrC2O4·H2O

**Solubility:** 
0.00433 g SrC2O4·H2O / 100 g H2O

**Molar Mass Calculation:**
(SrC2O4·H2O): 
- Sr: 87.62
- C: 12.01 x 2
- O: 16.00 x 4
- H2O: 18.01

Total molar mass = 193.65 g/mol

**Ksp from Solubility (Show your calculations below):**

\[ 5.00 \times 10^{-8} \]

Convert to moles:
\[ 
\frac{0.00433 \text{ g SrC2O4·H2O}}{193.65 \text{ g/mol}} = 2.2359 \times 10^{-5} \text{ mol} 
\]

Calculate molarity:
\[
\frac{2.2359 \times 10^{-5} \text{ mol}}{0.1 \text{ L}} \times \frac{1000 \text{ mL}}{1 \text{ L}} = 2.2359 \times 10^{-4} \text{ M}
\]

Dissociation:
\[ 
\text{SrC2O4} \rightarrow \text{Sr}^{2+} + \text{C2O4}^{2-} 
\]

Ksp:
\[ 
[\text{Sr}^{2+}] [\text{C2O4}^{2-}]
\]

Concentration of both Sr and C2O4 ions:
\[ 2.2359 \times 10^{-4} \, \text{M} \]

Ksp:
\[
\begin{align*}
2.2359 \times 10^{-4} \, \text{M} \times 2.2359 \times 10^{-4} \, \text{M} & = 4.9966 \times 10^{-8} \\
Ksp & = 5.00 \times 10^{-8}
\end{align*}
\]

**Calculate the molarity of KMnO4 solution needed to titrate 50.00 mL of a saturated solution
Transcribed Image Text:**Solubility Product Constant** **Identity of Oxalate Salt:** SrC2O4·H2O **Solubility:** 0.00433 g SrC2O4·H2O / 100 g H2O **Molar Mass Calculation:** (SrC2O4·H2O): - Sr: 87.62 - C: 12.01 x 2 - O: 16.00 x 4 - H2O: 18.01 Total molar mass = 193.65 g/mol **Ksp from Solubility (Show your calculations below):** \[ 5.00 \times 10^{-8} \] Convert to moles: \[ \frac{0.00433 \text{ g SrC2O4·H2O}}{193.65 \text{ g/mol}} = 2.2359 \times 10^{-5} \text{ mol} \] Calculate molarity: \[ \frac{2.2359 \times 10^{-5} \text{ mol}}{0.1 \text{ L}} \times \frac{1000 \text{ mL}}{1 \text{ L}} = 2.2359 \times 10^{-4} \text{ M} \] Dissociation: \[ \text{SrC2O4} \rightarrow \text{Sr}^{2+} + \text{C2O4}^{2-} \] Ksp: \[ [\text{Sr}^{2+}] [\text{C2O4}^{2-}] \] Concentration of both Sr and C2O4 ions: \[ 2.2359 \times 10^{-4} \, \text{M} \] Ksp: \[ \begin{align*} 2.2359 \times 10^{-4} \, \text{M} \times 2.2359 \times 10^{-4} \, \text{M} & = 4.9966 \times 10^{-8} \\ Ksp & = 5.00 \times 10^{-8} \end{align*} \] **Calculate the molarity of KMnO4 solution needed to titrate 50.00 mL of a saturated solution
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