Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:3.6 Experimental Determination of Empirical Formulas
13)The reaction of copper and sulfur at high heat creates a "copper sulfide". But does it create
copper (1) sulfide or cupric sulfide? An experiment is run in which Cu is heated over high heat in a
crucible, three times, in the presence of excess sulfur. The results are as follows.
Mass of crucible, cover, and copper sulfide = 26.512 g
Determine the formula for the "copper sulfide" created and give its name.
3.7 Chemical Reactions and Chemical Equations
14) Balance the following chemical equations by placing the correct coefficient in front of each
reactant/product. Research the physical state of each and add in the phase labels.
_Al4C3() + H2O() →
Al(OH)3()+ ___ CH4()
a)
Mass Empty Crucible and cover: 24.305 g
Mass Crucible and Cover and copper = 25.808 g
b)
c)
d)
C7H14() +.
02()→
CO2() +
- H₂00
CaSO4() +
Ca3(PO4)2()+ H2SO4()→
PC13() + H2O() → H3PO3() +.
4.5 mol H2 X
_H3PO40)
15) H2 and N2 react to form NH3 by the equation:
N2(g) + 3H2(g) → 2NH3 (g).
If a reaction vessel initially contained 300 H₂ molecules and 150 N2 molecules, which molecules
will be present in the vessel if the reaction proceeds to completion?
HClO
Speed Stoichiometry! Let's Focus on water _H2 + _O2 → _H₂O (Balance this first!)
Moles moles
Example: For the following reaction, how many moles of water can be made from 4.5 moles of hydrogen?
2 mol H₂O
2 mol H₂
How many moles of oxygen are needed to react with 3.5 moles of hydrogen?
How many moles of hydrogen are needed to react with 6 moles of oxygen?
How many moles of water are produced from with 12.5 moles of oxygen?
How many moles of water can be made from 4.5 moles of oxygen?
- 4.5 mol H2O

Transcribed Image Text:6) Calculate the molar mass of a compound if 0.372 mol of it has a mass of 152 g. See Problem 3.25
7) Calculate the number of ethane (C2H6) molecules in 0.334 g of ethane. See Problem 3.26
8) What is the mass in grams of a single atom of arsenic(As). See Problem 3.18
9) Calculate the mass of one arsenic atom using the mass of the proton and neutron.
3.4 Mass Spectrometry
10) Carbon has two stable isotopes, 12C and C, and fluorine has only one stable isotope, F.
13
6
19
9
6
How many peaks would you observe in the mass spectrum of the positive ion of CF4+. Assume that
the ion does not break up into smaller fragments. . See Problem 3.33 (Hint: Think of how many
different combinations of isotopes you could make)
3.5 Percent Composition of Compounds
11) For many years chloroform (CHC13) was used as an inhalation anesthetic in spite of the fact that it
is also a toxic substance that can cause severe liver, kidney, and heart damage. Calculate the
percent composition by mass of each element in this compound to four significant figures. See
Problem 3.40
12) Allicin is the compound responsible for the characteristic odor of garlic. An analysis of the
compound gives the following percent composition by mass: C: 44.4%, H: 6.21%, S: 39.5%, 0:
9.86% Calculate its empirical formula and molecular formula given its molar mass is 162 g/mol.
See Problem 3.43
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6) Given,
Number of moles=0.372
Mass=152 g
To calculate,
Molar mass
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