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Calculate the molar change in chemical potential of an ideal gas that expands by 10 times its orignal volume at a 100k

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter16: Spontaneity Of Reaction

Section: Chapter Questions

Problem 85QAP: Which of the following quantities can be taken to be independent of temperature? independent of...

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Calculate the molar change in chemical potential of the ideal gas that expands by 10 times its original volume at temperature 300 K.
the ionic compound L2O3(s) is the ionic compound formed from oxygen and a metal with the form L(s) at 1.00 bar and 298 K. (a) Draw the Lewis structure for L2O3. Assume that all the valence electrons from L are required. (b) Use the following information to determine the enthalpy of formation for L2O3(s). Express your answer in kJZ(mol L2O3(s)). Lattice energy for L2O3(s) = -14836 kJ mol1 AHsub for L(s) = 358 kJ mol 1 First ionization energy for L(g) = 577 kJ mol 1 Second ionization energy for L(g) = 1794 kJ mol 1 Third ionization energy for L(g) = 3820 kJ mol 1 Bond dissociation energy for O2(g) = 498 kJ mol 1 %3D First electron affinity for O = -141 kJ mol 1 Second electron affinity for O = 744 kJ mol 1
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1. Assume the molar Gibbs free energy of a gas is given by the equation: Gm - RT In(÷)+ (a + bT)P = 0, where po is the standard pressure and a and b are gas-dependent constants. Derive an equation of state for this gas. Show the final result in the form of PV=?.
6. When the ideal-gas reaction A+B=C+Dhas reached equilibrium, state whether or not each of the following relations must be true. Here n¡ is the number of moles of species i in equilibrium, P, is the partial pressure of i, and µ; is the chemical potential of i. Here a simple True or False answer is sufficient. (a) nc+np=nA +ng (b) Pc+Pp=PA+PB (c) na=ng (d) nc=na (e) If only A and B are present initially, then nc=np (f) Ha + HB= Hc+ Hp no matter what the initial composition. (g) If only A and B are present initially, then in equilibrium we must have nc # 0. (h) The equilibrium constant Kp(T)= PĄPB/(PcPp). (i) The value of –RT In Kp(T) = µE(T)+µ8(T)– H3(T) –- H§(T). ) The equilibrium constant is independent of the total pressure.
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