Calculate the mass flux (kg/m2-s) for the following tank leaks given that the storage pressure is equal to the vapor pressure at 25°C:   Toxic material Pressure (Pa) Heat of Vaporization (J/kg) vfg (m3/kg) Heat Capacity (J/kg-K) Propane 0.95 x 106 3.33 x 105 0.048 2.23 x 103 Ammonia 1 x 106 1.17 x 106 0.127 4.49 x 103 Methyl chloride 0.56 x 106 3.75 x 105 0.077 1.5 x 103 Sulfur dioxide 0.39 x 106 3.56 x 105 0.09 1.36 x 103

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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Textbook- Chemical Process Safety 5th ed.

Chapter 4.

The following question asks for a mass flux rate for a tank leak, but the size of the hole or oriface is not provided. All formulas in chapter 4 require an area A. Is there a way to solve this problem without the hole size?

 

Calculate the mass flux (kg/m2-s) for the following tank leaks given that the storage pressure is equal to the vapor pressure at 25°C:

 

Toxic material

Pressure (Pa)

Heat of Vaporization (J/kg)

vfg (m3/kg)

Heat Capacity (J/kg-K)

Propane

0.95 x 106

3.33 x 105

0.048

2.23 x 103

Ammonia

1 x 106

1.17 x 106

0.127

4.49 x 103

Methyl chloride

0.56 x 106

3.75 x 105

0.077

1.5 x 103

Sulfur dioxide

0.39 x 106

3.56 x 105

0.09

1.36 x 103

 

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