Chapter3: Organic Compounds: Alkanes And Their Stereochemistry
Section3.SE: Something Extra
Problem 47AP: Draw the most stable conformation of 1,4-dichlorobutane, using wedges and dashes to represent bonds...
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![Question 29
Calculate the energies of the 4 conformers below:
Me
H Me
Me
H.
H Me
Me
H.
H.
-Me
Me
H.
Me
Me
H
Mé
Ме
H.
Me
Erel
Erel =
Erel=
Erel
Me-Me Gauche: 3.8 kJ/mol; eclispsed H-H: 4 kJ/mol; eclipsed Me-H: 6.0 kJ/mol; eclipsed Me-Me: 11 kJ/mol
О 83B 23;B 0%;B 18
O 22; 18.8; 7.6; 18
O 7.6; 21; 3.8; 18
О 19.6;B 24.8;B 7.8;B 21.8](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Faf678f84-0a3c-4924-ab51-8cee374eafc3%2F96fa43e8-2921-4fad-8f8e-59fef2820332%2F8ees6p4_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Question 29
Calculate the energies of the 4 conformers below:
Me
H Me
Me
H.
H Me
Me
H.
H.
-Me
Me
H.
Me
Me
H
Mé
Ме
H.
Me
Erel
Erel =
Erel=
Erel
Me-Me Gauche: 3.8 kJ/mol; eclispsed H-H: 4 kJ/mol; eclipsed Me-H: 6.0 kJ/mol; eclipsed Me-Me: 11 kJ/mol
О 83B 23;B 0%;B 18
O 22; 18.8; 7.6; 18
O 7.6; 21; 3.8; 18
О 19.6;B 24.8;B 7.8;B 21.8
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