Calculate the degree of unsaturation of compound E. What information can be obtained from the calculated degree of unsaturation?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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a.Calculate the degree of unsaturation of compound E. What information can be obtained from the calculated degree of unsaturation?

b.Draw the most likely ion fragment for the signals at m/z 911, 139, and 156.

c.Why do these signals at 111, 139, 156, and 184 appear as pairs with the intensities of 1/3 at 113, 141, 158, and 186?

d.ldentify and draw the structure of compound E

The mass spectrum of Compound E is shown below.
100
Keamatan
Intensity
21.3
m/z
75.0
76.0
6.8
77.0
3.0
80
2.5
1.9
1.0
85.0
104.0
105.0
110.0
1.0
111.0
32.5
60
112.0
3.7
113.0
114.0
139.0
140.0
11.3
1.0
100.0
10.5
38.1
40
141.0
3.6
142.0
149.0
156.0
1.4
21.2
158.0
7.7
20
7.3
184.0
186.0
[M]+
C9H9CIO2
2.2
50
75
100
125
150
175
m/z
Relative Intensity
25
Transcribed Image Text:The mass spectrum of Compound E is shown below. 100 Keamatan Intensity 21.3 m/z 75.0 76.0 6.8 77.0 3.0 80 2.5 1.9 1.0 85.0 104.0 105.0 110.0 1.0 111.0 32.5 60 112.0 3.7 113.0 114.0 139.0 140.0 11.3 1.0 100.0 10.5 38.1 40 141.0 3.6 142.0 149.0 156.0 1.4 21.2 158.0 7.7 20 7.3 184.0 186.0 [M]+ C9H9CIO2 2.2 50 75 100 125 150 175 m/z Relative Intensity 25
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