Calculate the change in entropy of the system, surroundings and total change when a sample of nitrogen, mass 15 grams at 298 K doubles in volume in 1) an isothermal reversible reaction 2) an isothermal irreversible expansion against pex=0 and 3) an adiabatic reversible expansion.
Calculate the change in entropy of the system, surroundings and total change when a sample of nitrogen, mass 15 grams at 298 K doubles in volume in 1) an isothermal reversible reaction 2) an isothermal irreversible expansion against pex=0 and 3) an adiabatic reversible expansion.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Calculate the change in entropy of the system, surroundings and total change when a sample of nitrogen, mass 15 grams at 298 K doubles in volume in 1) an isothermal reversible reaction 2) an isothermal irreversible expansion against pex=0 and 3) an adiabatic reversible expansion.
Expert Solution
Step 1
We have to know the process like isothermal process means change in temperature is constant. Adiabatic process means there is no heat added or left in the system Q=0. For reversible isothermal expansion
∆Ssystem= -∆Ssorrounding
For irreversible isothermal expansion-
∆Ssurrounding=0
∆Ssystem=∆Stotal
For adiabatic reversible expansion
∆Ssystem= ∆Ssorrounding=∆Stotal =0
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