Calculate the absolute entropy, S CALOR, associated with sulphur dioxide gas at room temperature. Comment briefly on the accuracy of each contribution to the overall calculation.

Chemistry
10th Edition
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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(b)
Given the following information for sulphur dioxide gas:
15
CpdlnT
197.64
S₁
15
263.08
ľ
197.64
-
Cp dlnT
CpdlnT
1.25 J K-¹ mol-¹
=
84.18 J K¹ mol-¹
24.94 J K¹ mol-¹
Melting Point TMP=197.64 K, AHFUSION = 7.402 kJ mol™¹
Boiling Point, TBP = 263.08 K, AHVAP = 24.94 kJ mol-¹
Heat Capacity of SO2 (g), Cp = 39.87 J K ¹ mol¹.
Calculate the absolute entropy, SoCALOR, associated with sulphur dioxide gas at room
temperature. Comment briefly on the accuracy of each contribution to the overall
calculation.
Transcribed Image Text:(b) Given the following information for sulphur dioxide gas: 15 CpdlnT 197.64 S₁ 15 263.08 ľ 197.64 - Cp dlnT CpdlnT 1.25 J K-¹ mol-¹ = 84.18 J K¹ mol-¹ 24.94 J K¹ mol-¹ Melting Point TMP=197.64 K, AHFUSION = 7.402 kJ mol™¹ Boiling Point, TBP = 263.08 K, AHVAP = 24.94 kJ mol-¹ Heat Capacity of SO2 (g), Cp = 39.87 J K ¹ mol¹. Calculate the absolute entropy, SoCALOR, associated with sulphur dioxide gas at room temperature. Comment briefly on the accuracy of each contribution to the overall calculation.
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