) Calculate mass of the acid required to prepare 100 cm' of 0.1 solution of this acid.(Molar mass of the acid 150 g mol) 5) What is the volume of sodium hydroxide added at equivalence point?

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Chapter1: Chemical Foundations
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ANSWER BI AND ANY OTHER THREE QUESTIONS
SECTION D
Question B1
One way to delermine the pKa value is by use ofa pli curve. One student used thie pH curve
to determine thc pka value of the weak monoprotic acid. She transferred
25.0 cm' of
0.100 M solution of the acid into a conical flask and measured the pll of the acid solution
using a pH mcter accurate to one decimal place. A solution of sodium hydroxide of
concentration 0.100 mol dni was added from the burette in small portions until the alkali
was present in excess. The pH of the mixture was recorded after each addition of the sodium
hydroxide solution. Then she plotted the pH of the solution versus volume of alkali added
from the burette and used this graph to determine the acid dissociation constant.
14
12
10-
10
20
30
40
50
VNaOH (ml)
a) Calculate mass of the acid required to prepare 100 cm' of 0.1 solution of this
acid.(Molar mass of the acid 150 g mol)
b) What is the volume of sodium hydroxide added at cquivalence point?
c) What is the pH of the solution when half of the acid is neutralised
d) What is the pKa of the acid? Show all your calculations
c) Explain why pH changes slowly between point A and R
Transcribed Image Text:ANSWER BI AND ANY OTHER THREE QUESTIONS SECTION D Question B1 One way to delermine the pKa value is by use ofa pli curve. One student used thie pH curve to determine thc pka value of the weak monoprotic acid. She transferred 25.0 cm' of 0.100 M solution of the acid into a conical flask and measured the pll of the acid solution using a pH mcter accurate to one decimal place. A solution of sodium hydroxide of concentration 0.100 mol dni was added from the burette in small portions until the alkali was present in excess. The pH of the mixture was recorded after each addition of the sodium hydroxide solution. Then she plotted the pH of the solution versus volume of alkali added from the burette and used this graph to determine the acid dissociation constant. 14 12 10- 10 20 30 40 50 VNaOH (ml) a) Calculate mass of the acid required to prepare 100 cm' of 0.1 solution of this acid.(Molar mass of the acid 150 g mol) b) What is the volume of sodium hydroxide added at cquivalence point? c) What is the pH of the solution when half of the acid is neutralised d) What is the pKa of the acid? Show all your calculations c) Explain why pH changes slowly between point A and R
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