Calculate ΔHrxn values for the following equations using standard enthalpies of formation (ΔHof) data. CaCl2·2H2O (s) --> Ca2+(aq) + 2 Cl- (aq) + 2 H2O (l) (refer to image)
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
Calculate ΔHrxn values for the following equations using standard enthalpies of formation (ΔHof) data.
CaCl2·2H2O (s) --> Ca2+(aq) + 2 Cl- (aq) + 2 H2O (l)
(refer to image)
Calculate the percent error between your results and the ΔHrxn for CaCl2·2H2O (s). Discuss the results. Do you think the formation of a hydrate could explain some of the experimental error? Explain your answer.
Consider the given balanced reaction as;
Standard enthalpy of formation can be determined by using the given formula as;
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