Calcu la late pitofd alA solution thatis 0.070M in potassiem propienatel(2tscook or KC3 Hs02) an d 0.085Min prepienic acid ( C 2lts coolt or tC3lts Oz) ) A Sclution that iso.085Min trime thylamine (CH3)3N and O.1oM in trimethy lammonium. Chloride ( Cit3)s NCI. C) a solution that isma de by mixing 25.0mhck O. 20M acetic acid and 2S.UmL ef 0.25 M Sodium acetate. E CKa farpropionic acidis 1,3 X/0 trimethylamine kais 6.4 x10 5)

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Title: Calculating pH of Various Solutions

**Objective:** Calculate the pH of the following solutions:

a) **Solution Composition:**
   - 0.070 M in potassium propionate (C₂H₅COOK)
   - 0.085 M in propionic acid (C₂H₅COOH)
   - Note: \(K_a\) for propionic acid is \(1.3 \times 10^{-5}\).

b) **Solution Composition:**
   - 0.085 M in trimethylamine (CH₃)₃N
   - 0.10 M in trimethylammonium chloride (CH₃)₃NHCl
   - Note: \(K_b\) for trimethylamine is \(6.4 \times 10^{-5}\).

c) **Solution Construction:**
   - Made by mixing 25.0 mL of 0.20 M acetic acid and 25.0 mL of 0.25 M sodium acetate.

**Instructions:**

1. For solution (a), determine the pH by considering the relationship between the concentrations of the acid and its conjugate base, applying the Henderson-Hasselbalch equation.

2. For solution (b), calculate the pH using the concentration of the weak base and its salt, employing the Henderson-Hasselbalch equation for bases.

3. For solution (c), first identify the moles of acetic acid and sodium acetate mixed. Use the Henderson-Hasselbalch equation to find the resulting pH post-mixing.
Transcribed Image Text:Title: Calculating pH of Various Solutions **Objective:** Calculate the pH of the following solutions: a) **Solution Composition:** - 0.070 M in potassium propionate (C₂H₅COOK) - 0.085 M in propionic acid (C₂H₅COOH) - Note: \(K_a\) for propionic acid is \(1.3 \times 10^{-5}\). b) **Solution Composition:** - 0.085 M in trimethylamine (CH₃)₃N - 0.10 M in trimethylammonium chloride (CH₃)₃NHCl - Note: \(K_b\) for trimethylamine is \(6.4 \times 10^{-5}\). c) **Solution Construction:** - Made by mixing 25.0 mL of 0.20 M acetic acid and 25.0 mL of 0.25 M sodium acetate. **Instructions:** 1. For solution (a), determine the pH by considering the relationship between the concentrations of the acid and its conjugate base, applying the Henderson-Hasselbalch equation. 2. For solution (b), calculate the pH using the concentration of the weak base and its salt, employing the Henderson-Hasselbalch equation for bases. 3. For solution (c), first identify the moles of acetic acid and sodium acetate mixed. Use the Henderson-Hasselbalch equation to find the resulting pH post-mixing.
Expert Solution
Step 1

All the solutions contain weak acid and its conjugate base. So, these are buffer solutions.

pH of the buffer solution is determined by Henderson equation.

pH=pKa+log[conjugate base][acid]

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