(C9H12) IS produced from (9H92) propylen main intermediate in a process that generates the majority of phenol and acetone globally. Please see the diagram for this continuous steady-state process below. Cumene synthesis (Reaction 1) occurs in the gas phase within a reactor with an immobilized catalyst. The main undesired product. are diisopropylbenzenes (Reaction 2). To reduce undesired reactions, benzene enters the reactor at 325% molar excess. Following the reactor, the effluent enters a condenser where the excess benzene and propylene are retrieved as the vapor product and recycled back to mix with fresh benzene and propylene before entering the reactor. The liquid product is composed of cumene and diisopropylbenzenes that then proceed to additional separation units. Reaction 1: C,Ho(8) + C3H6 (g) → C9H12 (8) Reaction 2: C,Ho (g) + 2 C3H6 (g) → C12H18 (8) a) as Sime that a' it ider vi hat th s inf f 38 ai on cti 1 or di du b) Calculate the standard heats of reactions for Reactions 1 and 2. Please note that the standard heats of formation for C9H12 (g) and C12H18 (g) are 3.90 kJ/mole and -76.51 kJ/mole, respectively. Please calculate the rate in kW at which heat needs to be supplied or removed from the reactor to ensure that it operates isothermally. Please approximate the constant pressure heat capacity of diisopropylbenzenes with that of toluene and use the heat of reaction method for this energy balance.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Cumene (C9H12) is produced from benzene (C6H6) and propylene (C3H6) as the
main intermediate in a process that generates the majority of phenol and acetone globally. Please
Problem 3)
see the diagram for this continuous steady-state process below. Cumene synthesis (Reaction 1)
occurs in the gas phase within a reactor with an immobilized catalyst. The main undesired products
are diisopropylbenzenes (Reaction 2). To reduce undesired reactions, benzene enters the reactor at
325% molar excess. Following the reactor, the effluent enters a condenser where the excess
benzene and propylene are retrieved as the vapor product and recycled back to mix with fresh
benzene and propylene before entering the reactor. The liquid product is composed of cumene and
diisopropylbenzenes that then proceed to additional separation units.
Reaction 1: C,Ho (g) + C3H6 (g) → C9H12 (g)
Reaction 2: C,Ho (g) + 2 C3H6 (g) → C12H18 (8)
a) as
Sume that
it ider
's inf
vi
ihat th
O'
f
WI
38
ai
on
cti
or
di
du
b) Calculate the standard heats of reactions for Reactions 1 and 2. Please note that the standard
heats of formation for C,H12 (g) and C12H18 (g) are 3.90 kJ/mole and -76.51 kJ/mole, respectively.
Please calculate the rate in kW at which heat needs to be supplied or removed from the reactor to
ensure that it operates isothermally. Please approximate the constant pressure heat capacity of
diisopropylbenzenes with that of toluene and use the heat of reaction method for this energy
balance.
Transcribed Image Text:Cumene (C9H12) is produced from benzene (C6H6) and propylene (C3H6) as the main intermediate in a process that generates the majority of phenol and acetone globally. Please Problem 3) see the diagram for this continuous steady-state process below. Cumene synthesis (Reaction 1) occurs in the gas phase within a reactor with an immobilized catalyst. The main undesired products are diisopropylbenzenes (Reaction 2). To reduce undesired reactions, benzene enters the reactor at 325% molar excess. Following the reactor, the effluent enters a condenser where the excess benzene and propylene are retrieved as the vapor product and recycled back to mix with fresh benzene and propylene before entering the reactor. The liquid product is composed of cumene and diisopropylbenzenes that then proceed to additional separation units. Reaction 1: C,Ho (g) + C3H6 (g) → C9H12 (g) Reaction 2: C,Ho (g) + 2 C3H6 (g) → C12H18 (8) a) as Sume that it ider 's inf vi ihat th O' f WI 38 ai on cti or di du b) Calculate the standard heats of reactions for Reactions 1 and 2. Please note that the standard heats of formation for C,H12 (g) and C12H18 (g) are 3.90 kJ/mole and -76.51 kJ/mole, respectively. Please calculate the rate in kW at which heat needs to be supplied or removed from the reactor to ensure that it operates isothermally. Please approximate the constant pressure heat capacity of diisopropylbenzenes with that of toluene and use the heat of reaction method for this energy balance.
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