C6H5 OO Br od od B) C6H6, AlCl3 C6H5MgBr diethyl ether D) (C6H5)2Culi diethyl ether C6H,Br, AlCl3

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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1-phenylnaphthalene, shown below, can be prepared in over 80%yield by one of the reactions below. which one? explanation for your choice. 

 

 

C6H5
Br
.cd
A)
CI
C6H6, AlCl3
C6H5MgBr
diethyl ether
B)
D)
(C6H5)2Culi
diethyl ether
C6H,Br, AlCl3
Transcribed Image Text:C6H5 Br .cd A) CI C6H6, AlCl3 C6H5MgBr diethyl ether B) D) (C6H5)2Culi diethyl ether C6H,Br, AlCl3
Expert Solution
Step 1

The question is given how  1-phenylnapthalene is prepared and what is the correct way to formation of the product in the given options .

The method of a coupling of alkyl halides with dialkyl copper reagent is called the Corey-House synthesis reaction. It involves the coupling of alkyl halides to generate higher hydrocarbons. Dialkyl copper lithium reagent is also known Gilman reagent. 

The general reaction is given as

 R2CuLi  +  R ′ -X     →   R-R ′ +      R-Cu   +    LiX

 

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