Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
1-phenylnaphthalene, shown below, can be prepared in over 80%yield by one of the reactions below. which one? explanation for your choice.
![C6H5
Br
.cd
A)
CI
C6H6, AlCl3
C6H5MgBr
diethyl ether
B)
D)
(C6H5)2Culi
diethyl ether
C6H,Br, AlCl3](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fa76dca97-a897-41bf-b1da-dc4488871ea8%2F3afb04c8-d89a-4b30-9c4a-2019a1490f86%2Fzbfarr_processed.png&w=3840&q=75)
Transcribed Image Text:C6H5
Br
.cd
A)
CI
C6H6, AlCl3
C6H5MgBr
diethyl ether
B)
D)
(C6H5)2Culi
diethyl ether
C6H,Br, AlCl3
Expert Solution
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Step 1
The question is given how 1-phenylnapthalene is prepared and what is the correct way to formation of the product in the given options .
The method of a coupling of alkyl halides with dialkyl copper reagent is called the Corey-House synthesis reaction. It involves the coupling of alkyl halides to generate higher hydrocarbons. Dialkyl copper lithium reagent is also known Gilman reagent.
The general reaction is given as
R2CuLi + R ′ -X → R-R ′ + R-Cu + LiX
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