(c). What is the dynamic range of the method? Hint: it is NOT the entire concentration range. (d). A sample of water yielded an absorbance of 0.36. What is the concentration of As in the water?

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter7: Statistical Data Treatment And Evaluation
Section: Chapter Questions
Problem 7.8QAP
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Solve (c) and (d)

A graphite furnace atomic absorption spectrophotometer (AAS) was used to determine the
arsenic (As) concentrations in drinking water. A large set of blank samples yielded an average
blank signal of 0.015 and a blank standard deviation of 0.0050. The following data were
obtained for a calibration curve.
[As] (ppm)
2.0
4.0
6.0
8.0
10.0
Absorbance
0.15
0.27
0.46
0.55
0.71
Using a spreadsheet on an Excel, create a graph of the data using symbols only for the data
points. Plot the line on the same graph and include the graph to this question. Answer the
following questions.
(a). What is the sensitivity of the method?
(b). Calculate the LOD and LOQ for As.
(c). What is the dynamic range of the method? Hint: it is NOT the entire
concentration range.
(d). A sample of water yielded an absorbance of 0.36. What is the concentration of
As in the water?
Transcribed Image Text:A graphite furnace atomic absorption spectrophotometer (AAS) was used to determine the arsenic (As) concentrations in drinking water. A large set of blank samples yielded an average blank signal of 0.015 and a blank standard deviation of 0.0050. The following data were obtained for a calibration curve. [As] (ppm) 2.0 4.0 6.0 8.0 10.0 Absorbance 0.15 0.27 0.46 0.55 0.71 Using a spreadsheet on an Excel, create a graph of the data using symbols only for the data points. Plot the line on the same graph and include the graph to this question. Answer the following questions. (a). What is the sensitivity of the method? (b). Calculate the LOD and LOQ for As. (c). What is the dynamic range of the method? Hint: it is NOT the entire concentration range. (d). A sample of water yielded an absorbance of 0.36. What is the concentration of As in the water?
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