(c) The data set below represents the surface tension data for aqueous solutions of 3- methylbutanoic acid [(CH3)2CHCH₂COOH] at 25°C. [C] [mol.dm³] 0 Y [mN.m'] 0.009 72.7 64.6 0.026 59.0 0.065 51.3 0.135 47.0 (i) Calculate the surface excess of 3-methylbutanoic acid (in mol.m²) and (ii) Hence estimate the molecular cross sectional area (in nm²) for this surface active molecule. (iii) Compare your estimate with the molecular cross sectional area one might expect for n-butanoic acid and account for the difference, if any, between the two surface active molecules.
(c) The data set below represents the surface tension data for aqueous solutions of 3- methylbutanoic acid [(CH3)2CHCH₂COOH] at 25°C. [C] [mol.dm³] 0 Y [mN.m'] 0.009 72.7 64.6 0.026 59.0 0.065 51.3 0.135 47.0 (i) Calculate the surface excess of 3-methylbutanoic acid (in mol.m²) and (ii) Hence estimate the molecular cross sectional area (in nm²) for this surface active molecule. (iii) Compare your estimate with the molecular cross sectional area one might expect for n-butanoic acid and account for the difference, if any, between the two surface active molecules.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![(c) The data set below represents the surface tension data for aqueous solutions of 3-
methylbutanoic acid [(CH3)2CHCH₂COOH] at 25°C.
[C] [mol.dm³] 0
Y[mN.m']
72.7
0.009
64.6
0.026
59.0
0.065
51.3
0.135
47.0
(i) Calculate the surface excess of 3-methylbutanoic acid (in mol.m2) and
(ii)
Hence estimate the molecular cross sectional area (in nm²) for this surface active
molecule.
(iii) Compare your estimate with the molecular cross sectional area one might expect
for n-butanoic acid and account for the difference, if any, between the two surface
active molecules.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fd8fa6a66-eb5a-48e4-9b45-07098ecf6f3f%2Fcb9da43e-fdf1-4d1c-9749-c51ced9fb047%2Fsohnvs_processed.jpeg&w=3840&q=75)
Transcribed Image Text:(c) The data set below represents the surface tension data for aqueous solutions of 3-
methylbutanoic acid [(CH3)2CHCH₂COOH] at 25°C.
[C] [mol.dm³] 0
Y[mN.m']
72.7
0.009
64.6
0.026
59.0
0.065
51.3
0.135
47.0
(i) Calculate the surface excess of 3-methylbutanoic acid (in mol.m2) and
(ii)
Hence estimate the molecular cross sectional area (in nm²) for this surface active
molecule.
(iii) Compare your estimate with the molecular cross sectional area one might expect
for n-butanoic acid and account for the difference, if any, between the two surface
active molecules.
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