By titration, it is found that 29.9 mL of 0.108 M NaOH(aq) is needed to neutralize 25.0 mL of HCl(aq). Calculate the concentration of the HCl solution. [HCI] = M

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**Titration Problem: Calculating the Concentration of an HCl Solution**

By titration, it is found that 29.9 mL of 0.108 M NaOH(aq) is needed to neutralize 25.0 mL of HCl(aq). Calculate the concentration of the HCl solution.

\[[\text{HCl}] = \_\_\_\_\_\_\_\_ \text{M} \]

**Explanation:**
To find the concentration of the HCl solution, use the concept of molarity and the titration formula:

1. Begin with the balanced chemical equation for the reaction:
   \[
   \text{HCl} + \text{NaOH} \rightarrow \text{NaCl} + \text{H}_2\text{O}
   \]
   Each mole of HCl reacts with one mole of NaOH.

2. Calculate moles of NaOH used:
   \[
   \text{Moles of NaOH} = \text{Volume (L)} \times \text{Molarity} = 0.0299 \, \text{L} \times 0.108 \, \text{M} = 0.0032292 \, \text{mol}
   \]

3. Since the molar ratio of HCl to NaOH is 1:1, moles of HCl = moles of NaOH = 0.0032292 mol.

4. Calculate the molarity of the HCl solution:
   \[
   [\text{HCl}] = \frac{\text{Moles of HCl}}{\text{Volume of HCl (L)}} = \frac{0.0032292 \, \text{mol}}{0.025 \, \text{L}} = 0.129168 \, \text{M}
   \]

Thus, the concentration of the HCl solution is approximately 0.129 M.

**Source:** McQuarrie, Rock, and Gallogly 4e – General Chemistry  
**Publisher:** University Science Books
Transcribed Image Text:**Titration Problem: Calculating the Concentration of an HCl Solution** By titration, it is found that 29.9 mL of 0.108 M NaOH(aq) is needed to neutralize 25.0 mL of HCl(aq). Calculate the concentration of the HCl solution. \[[\text{HCl}] = \_\_\_\_\_\_\_\_ \text{M} \] **Explanation:** To find the concentration of the HCl solution, use the concept of molarity and the titration formula: 1. Begin with the balanced chemical equation for the reaction: \[ \text{HCl} + \text{NaOH} \rightarrow \text{NaCl} + \text{H}_2\text{O} \] Each mole of HCl reacts with one mole of NaOH. 2. Calculate moles of NaOH used: \[ \text{Moles of NaOH} = \text{Volume (L)} \times \text{Molarity} = 0.0299 \, \text{L} \times 0.108 \, \text{M} = 0.0032292 \, \text{mol} \] 3. Since the molar ratio of HCl to NaOH is 1:1, moles of HCl = moles of NaOH = 0.0032292 mol. 4. Calculate the molarity of the HCl solution: \[ [\text{HCl}] = \frac{\text{Moles of HCl}}{\text{Volume of HCl (L)}} = \frac{0.0032292 \, \text{mol}}{0.025 \, \text{L}} = 0.129168 \, \text{M} \] Thus, the concentration of the HCl solution is approximately 0.129 M. **Source:** McQuarrie, Rock, and Gallogly 4e – General Chemistry **Publisher:** University Science Books
Expert Solution
Step 1

Given -

Volume of NaOH= 29.9 mL = V1 

Concentration of NaOH= 0.1 08 M = M1

Volume of HCl =25.0 mL = V2 

 

 

 

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