**Understanding Half-Life and Its Derivation:** **Concept of Half-Life:** Half-life is the time required for a quantity to reduce to half its initial value. It is commonly associated with the decay of radioactive materials, but it also applies to various exponential decay processes, such as chemical reactions and pharmacokinetics. **Deriving Half-Life Formula for Zero-Order Decay:** A zero-order reaction is one where the rate of reaction is constant and independent of the concentration of the reactant. The rate law for a zero-order reaction can be expressed as: \[ \frac{d[A]}{dt} = -k \] Where: - \([A]\) is the concentration of the reactant - \(k\) is the rate constant - \(t\) is time Rearranging and integrating from \([A]_0\) to \([A]\) and from 0 to \(t\), the expression becomes: \[ [A] = [A]_0 - kt \] To find the half-life (\(t_{1/2}\)), set \([A] = \frac{[A]_0}{2}\): \[ \frac{[A]_0}{2} = [A]_0 - kt_{1/2} \] Solving for \(t_{1/2}\), we get: \[ t_{1/2} = \frac{[A]_0}{2k} \] This formula indicates that for a zero-order reaction, the half-life is directly proportional to the initial concentration \([A]_0\) and inversely proportional to the rate constant \(k\).

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ISBN:9781337630931
Author:KASSIMALI, Aslam.
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Chapter2: Loads On Structures
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**Understanding Half-Life and Its Derivation:**

**Concept of Half-Life:**
Half-life is the time required for a quantity to reduce to half its initial value. It is commonly associated with the decay of radioactive materials, but it also applies to various exponential decay processes, such as chemical reactions and pharmacokinetics.

**Deriving Half-Life Formula for Zero-Order Decay:**

A zero-order reaction is one where the rate of reaction is constant and independent of the concentration of the reactant. The rate law for a zero-order reaction can be expressed as:

\[ \frac{d[A]}{dt} = -k \]

Where:
- \([A]\) is the concentration of the reactant
- \(k\) is the rate constant
- \(t\) is time

Rearranging and integrating from \([A]_0\) to \([A]\) and from 0 to \(t\), the expression becomes:

\[ [A] = [A]_0 - kt \]

To find the half-life (\(t_{1/2}\)), set \([A] = \frac{[A]_0}{2}\):

\[ \frac{[A]_0}{2} = [A]_0 - kt_{1/2} \]

Solving for \(t_{1/2}\), we get:

\[ t_{1/2} = \frac{[A]_0}{2k} \]

This formula indicates that for a zero-order reaction, the half-life is directly proportional to the initial concentration \([A]_0\) and inversely proportional to the rate constant \(k\).
Transcribed Image Text:**Understanding Half-Life and Its Derivation:** **Concept of Half-Life:** Half-life is the time required for a quantity to reduce to half its initial value. It is commonly associated with the decay of radioactive materials, but it also applies to various exponential decay processes, such as chemical reactions and pharmacokinetics. **Deriving Half-Life Formula for Zero-Order Decay:** A zero-order reaction is one where the rate of reaction is constant and independent of the concentration of the reactant. The rate law for a zero-order reaction can be expressed as: \[ \frac{d[A]}{dt} = -k \] Where: - \([A]\) is the concentration of the reactant - \(k\) is the rate constant - \(t\) is time Rearranging and integrating from \([A]_0\) to \([A]\) and from 0 to \(t\), the expression becomes: \[ [A] = [A]_0 - kt \] To find the half-life (\(t_{1/2}\)), set \([A] = \frac{[A]_0}{2}\): \[ \frac{[A]_0}{2} = [A]_0 - kt_{1/2} \] Solving for \(t_{1/2}\), we get: \[ t_{1/2} = \frac{[A]_0}{2k} \] This formula indicates that for a zero-order reaction, the half-life is directly proportional to the initial concentration \([A]_0\) and inversely proportional to the rate constant \(k\).
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