Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Propose a synthesis for the compounds below using the reagents given below.
Transcribed Image Text:### Reagents (not necessarily a complete list):
- **PCC**
- **1. OsO₄; 2. KHSO₃**
- **MsCl (or TsCl), pyridine**
- **1. LiAlH₄; 2. H₃O⁺**
- **NaH**
- **SOCl₂**
- **TBDMS-Cl or TMS-Cl, Et₃N**
- **1. RSH, H⁺; 2. Raney Ni**
- **1. Hg(O₂CCF₃)₂, ROH; 2. NaBH₄**
- **POCl₃, pyridine**
- **PBr₃**
- **1. RMgX or RLi; 2. H₃O⁺**
- **NaBH₄**
- **mCPBA**
- **CrO₃, H₂SO₄, H₂O**
- **H⁺, ROH**
- **NaIO₄**
- **HX (X = Halogen)**
- **X₂**
- **1. Hg(OAc)₂, H₂O; 2. NaBH₄**
- **1. H⁺, H₂NNH₂; 2. NaOH**
- **H₂, Lindlar’s catalyst**
- **NaNH₂**
- **1. O₃; 2. Zn, HOAc**
- **1. BH₃-THF; 2. H₂O₂, NaOH**
- **H₂, Pd/C**
- **1. O₃; 2. H₂O**
- **Na, NH₃**
This list includes a variety of reagents commonly used in organic chemistry for different reactions such as oxidation, reduction, protection, and other transformations.
Transcribed Image Text:The image depicts a chemical reaction involving organic compounds.
On the left side, there is a reactant: a benzene ring attached to a bromine atom (C6H5-CH2-Br), commonly referred to as benzyl bromide.
The reaction is shown with a rightward arrow, indicating the transformation of the reactant into a product.
On the right side, the product is shown: a benzene ring attached to a propyl group terminating in a methoxy group (C6H5-CH2-CH(CH3)-OCH3).
This reaction suggests a substitution process where the bromine in benzyl bromide is replaced by a methoxypropyl group.
The diagram does not include specific conditions or reagents necessary for the reaction, such as catalysts, solvents, temperature, or pressure, which are essential for carrying out the substitution.
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