بمہر Conditions 1 Intermediate after Step 1 2. H 1. LAP 2. H 2.14.0₂ Conditions 2 Intermediate after Step 2 MOCI A D G ? 4 Stepe M OPBA 1. 004 2 50, GO, HỘ 1.500 p 2. Mg 1.H₂SO₂ H₂O 2. NH Conditions 3 N Q en T Conditions 4 Intermediate after Step 3 H50, heat tym 1. DIBA-H, -78 C 2. H ey 2. H hom с L 0 R de

Chemistry: The Molecular Science
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Chapter11: Chemical Kinetics: Rates Of Reactions
Section: Chapter Questions
Problem 6QRT
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For the following is a 4-step synthesis problem, you are given: the Starting Material and the Product; a scheme of the expected conditions/intermediates and a list of 21 possible conditions and intermediates. Put the correct conditions/intermediates in the correct order to achieve this transformation.
¡¡¡
¡¡¡
Intermediate 3
Intermediate 1
Conditions 2
Conditions 4
Conditions 3
Conditions 1
Intermediate 2
1.
2.
3.
4.
5.
6.
7.
8.
9.
Choice A
Choice B
Choice C
Choice D
Choice E
Choice F
Choice G
Choice H
Choice I
10. Choice J
11. Choice K
12. Choice L
13. Choice M
14. Choice N
15. Choice O
16. Choice P
17. Choice Q
18. Choice R
19. Choice S
20. Choice T
21. Choice U
Transcribed Image Text:¡¡¡ ¡¡¡ Intermediate 3 Intermediate 1 Conditions 2 Conditions 4 Conditions 3 Conditions 1 Intermediate 2 1. 2. 3. 4. 5. 6. 7. 8. 9. Choice A Choice B Choice C Choice D Choice E Choice F Choice G Choice H Choice I 10. Choice J 11. Choice K 12. Choice L 13. Choice M 14. Choice N 15. Choice O 16. Choice P 17. Choice Q 18. Choice R 19. Choice S 20. Choice T 21. Choice U
Conditions 1
Intermediate
after Step 1
1.
2. H*
OH
OH
1. LAH
2. H
OH
h
1.BH₂
2. H₂O₂
Conditions 2
MgCl
A
D
G
M
P
S
?
4 Steps
Intermediate
after Step 2
PPPG
MCPBA
OH
1. 0804
2. NaHSO,
GỌI HOT
1.800 py
2. Mg
1. HgSO4 H₂O
2. NaBH
Conditions 3
B
H
K
N
T
Conditions 4
Intermediate
after Step 3
H₂SO, heat
tyt
1. DIBA-H, -78 C
2. H
lym
1.
2. H
MOH
(3
с
maw
L
O
R
U
Transcribed Image Text:Conditions 1 Intermediate after Step 1 1. 2. H* OH OH 1. LAH 2. H OH h 1.BH₂ 2. H₂O₂ Conditions 2 MgCl A D G M P S ? 4 Steps Intermediate after Step 2 PPPG MCPBA OH 1. 0804 2. NaHSO, GỌI HOT 1.800 py 2. Mg 1. HgSO4 H₂O 2. NaBH Conditions 3 B H K N T Conditions 4 Intermediate after Step 3 H₂SO, heat tyt 1. DIBA-H, -78 C 2. H lym 1. 2. H MOH (3 с maw L O R U
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