Bismuth forms two fluorides: BiF3 and BiF5. As is usually the case, the compound with the metal in the lower oxidation state has more ionic character,whereas that with the metal in the higher oxidation state has more covalent (molecular) character. Predict which bismuth fluoride will have the higher boiling point.

Chemistry: The Molecular Science
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ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter19: The Chemistry Of The Main-group Elements
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Bismuth forms two fluorides: BiF3 and BiF5. As is usually the case, the compound with the metal in the lower oxidation state has more ionic character,whereas that with the metal in the higher oxidation state has more covalent (molecular) character. Predict which bismuth fluoride will have the higher boiling point.

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