Based on the IR spectra for (R/S)-2, need help with the following question. Thank you :) (mechanism provided to show what (R/S)-2 is)

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Based on the IR spectra for (R/S)-2, need help with the following question. Thank you :) (mechanism provided to show what (R/S)-2 is)

 

a) Provide an assignment for the IR spectra provided in Moodle for the (R/S)-2 using the following
table.
entry
wavenumber
strength
functional group
1
3
4
5
(add rows as needed)
Transcribed Image Text:a) Provide an assignment for the IR spectra provided in Moodle for the (R/S)-2 using the following table. entry wavenumber strength functional group 1 3 4 5 (add rows as needed)
OAc
-CO2ET
OCH3
(i) dil aq. HCI, 70 °C
Lipase PS,
t-BUOCH3, 168 h
он (S)-2
OH
+
(ii) K2CO3, 168 h
OCH3
II
1
Eto-P
EtO
.CO̟Et
OAc 3
ОН
(R/S)-2
Figure 2.2: Synthesis of (R/S)-2 and kinetic resolution with lipase PS.
Agilent Resolutions Pro
AW Lipase RAC alcohol
100
90-
80
70
60
50-
40-
30
3400
3200
3000
2600
2400
2200
2000
1800
1600
1400
1200
1000
800
Wavenumber
Name
AW Lipase RAC alcohol
%Transmittance
982
Transcribed Image Text:OAc -CO2ET OCH3 (i) dil aq. HCI, 70 °C Lipase PS, t-BUOCH3, 168 h он (S)-2 OH + (ii) K2CO3, 168 h OCH3 II 1 Eto-P EtO .CO̟Et OAc 3 ОН (R/S)-2 Figure 2.2: Synthesis of (R/S)-2 and kinetic resolution with lipase PS. Agilent Resolutions Pro AW Lipase RAC alcohol 100 90- 80 70 60 50- 40- 30 3400 3200 3000 2600 2400 2200 2000 1800 1600 1400 1200 1000 800 Wavenumber Name AW Lipase RAC alcohol %Transmittance 982
Expert Solution
Step 1

IR spectroscopy is an important tool to know the type of functionality present in a molecule. 

Stretching of the molecule appears at higher wave number than the bending one. 

steps

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