Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![B. Determination of the hydrolysis constant (or acid dissociation constant,
Ka) of NH4+.
1. Consider a 0.01 M NH4CI solution.
2. Write the dissociation equation for NH4CI.
3. Identify the ion/s that can undergo hydrolysis.
4. It has been determined experimentally that the pH of 0.01 M NH4CI solution is
5.91. From the pH of the solution, solve for the concentration of all species
present in the solution. Input all your answers in Tables 2 and 3.
5. Solve for the Ka of NH4+.
6. Compare your experimental value to the literature value for the Ka of NH4+.
B. Determination of the hydrolysis constant (or acid dissociation constant,
Ka) of NH4*.
Table 2. Dissociation of NH,CI
Dissociation equation of NH4CI
pH of solution
lon that undergoes hydrolysis:
Hydrolysis reaction
Table 3. ICE Table for the Hydrolysis of NH4*
Parameter
[NH,*]
[H*]
[NH3]
Initial concentration
Change in
concentration
Equilibrium
Concentration
Solving for the hydrolysis constant, Kn (or Ka) of NH4+
Theoretical Value for Ka of NH4+
% Error:](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F76e305a4-5257-4a32-9fe7-8aaad4dea0c8%2Ffb32ab5b-274d-4e6c-a2ec-ce3a54f17e84%2Fm5kzfii_processed.jpeg&w=3840&q=75)
Transcribed Image Text:B. Determination of the hydrolysis constant (or acid dissociation constant,
Ka) of NH4+.
1. Consider a 0.01 M NH4CI solution.
2. Write the dissociation equation for NH4CI.
3. Identify the ion/s that can undergo hydrolysis.
4. It has been determined experimentally that the pH of 0.01 M NH4CI solution is
5.91. From the pH of the solution, solve for the concentration of all species
present in the solution. Input all your answers in Tables 2 and 3.
5. Solve for the Ka of NH4+.
6. Compare your experimental value to the literature value for the Ka of NH4+.
B. Determination of the hydrolysis constant (or acid dissociation constant,
Ka) of NH4*.
Table 2. Dissociation of NH,CI
Dissociation equation of NH4CI
pH of solution
lon that undergoes hydrolysis:
Hydrolysis reaction
Table 3. ICE Table for the Hydrolysis of NH4*
Parameter
[NH,*]
[H*]
[NH3]
Initial concentration
Change in
concentration
Equilibrium
Concentration
Solving for the hydrolysis constant, Kn (or Ka) of NH4+
Theoretical Value for Ka of NH4+
% Error:
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