At high concentrations of [H2] the observed rate law is found to change to the form: Rate = k[NO]? i.e. the rate becomes independent of [H2]. Assess whether the two step mechanism that you showed to be plausible at lower[H2] concentrations in the pre- problem can also explain this additional data. Reexamine the mechanism in the Pre-recitation Problem: 2NO + H2 → O+ H2O + N2 slow ki 0+ H2 → H2O k2 Write the forward rates for both steps.

At high concentrations of [H2] the observed rate law is found to change to the form: Rate = k[NO]? i.e. the rate becomes independent of [H2]. Assess whether the two step mechanism that you showed to be plausible at lower[H2] concentrations in the pre- problem can also explain this additional data. Reexamine the mechanism in the Pre-recitation Problem: 2NO + H2 → O+ H2O + N2 slow ki 0+ H2 → H2O k2 Write the forward rates for both steps.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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