At 37 °C, calculate the standard free energy change for the reaction as written. 1,3-Bisphosphoglycerate + ADP →ATP + 3-Phosphoglycerate + H+: AH = 41.02 kJ/mol and AS = 0.3030 kJ/molk. All answers should be in units of kJ/mol Type your answer...
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At 37 oC, calculate the standard free energy change for the reaction as written.
1,3-Bisphosphoglycerate + ADP →ATP + 3-Phosphoglycerate + H+:
ΔH = 41.02 kJ/mol and ΔS = 0.3030 kJ/molK.
All answers should be in units of kJ/mol
Step by step
Solved in 2 steps
- At what temperature is this reaction at equilibrium? 1,3-Bisphosphoglycerate + ADP →ATP + 3-Phosphoglycerate + H+: ΔH = 41.02 kJ/mol and ΔS = 0.3030 kJ/molK. All answers should be in units of KelvinGiven that the reaction of 4 NH3 (g) + 5 O2 (g) → 4 NO (g) + 3 H20 (g) ΔΗ - - 906 kJ What would AH for NO (g) + ? H20 (g) → NH3 (g) + O2 (g) be? 2. 906 kJ 226.5 kJ -226.5kJ 453 kJCalculate the equilibrium constants Keqo for the following reactions, using the standard free energy changes given below. (Note: if your calculation produces an overflow error, give the answer as a power of e.)a) Glucose + 6O2 --> 6CO2 + 6H2O (–2,840 kJ/mol)b) ATP + H2O --> ADP + Pi (–30.5 kJ/mol)c) Ethyl Acetate + H2O --> Ethanol + Acetate (+19.6 kJ/mol)
- The standard free energy change for the reaction catalyzed by phosphoglucomutase is -7.1kJ/mol, (a) Calculate the equilibrium constant for the reaction, (b) Calculate ΔG at 37°C when the concentration of glucose-1-phosphate is 1-mM and the concentration of glucose-6-phosphate is 25-mM, (c) Is the reaction spontaneous under these conditions?In glycolysis, the reaction of glucose (Glu) to form glucose-6-phosphate (G6P) requires ATP to be present as described by the following equation: Glu+ ATP→G6) + ADP AG° = - 17KJ In this process, ATP becomes ADP summarized by the following equation: ATP→ ADP A G° =- 30 kJ What is the standard free energy change for the following reaction: Glu →G6P AG° =? A 17 k) B) -13 k) c) 13 kJ -17 kJ4
- The conversion of glucose (C,H12O6) into lactic acid (2CH3CH(OH)COOH) drives the phosphorylation of 2 moles of ADP to ATP and has a AG° = -135 kJ/mol. CH,0,(aq) + 2HPO? (aq) + 2ADP³3- (aq) +2H*(aq) –→ 2CH,CH(OH)COOH(aq) +2ATPª¯(ag) + 2H,0(1) The conversion of ATP to ADP has a AG° = -30.5 kJ/mol. ATP4 (ag)+H,0(1) –→ ADP³-(aq) + HPO? (aq) + H*(aq) 1st attempt See Periodic Tabl O See Hint What is AG° for the conversion of glucose into lactic acid? CH1206(aq) → 2CH,CH(OH)COOH(aq) A SUBMIT ANSWEREnergy from ATP hydrolysis drives many nonspontaneouscell reactions:AT P⁴⁻(aq) +H₂O(l) ⇌ADP³⁻(aq) +HPO₄²⁻(aq) +H(aq) ΔG°'=-30.5 kJ Energy for the reverse process comes ultimately from glucose metabolism:C₆H₁₂O₆(s)+ 6O₂g) →6CO₂(g) +6H₂O(l)(a) Find K for the hydrolysis of ATP at 37°C.(b) Find ΔG'°ᵣₙₓ for metabolism of 1 mol of glucose. (c) How many moles of ATP can be produced by metabolism of1 mol of glucose? (d) If 36 mol of ATP is formed, what is the actual yield?Please help as soon as you can. Thanks.
- In glycolysis, the enzyme pyruvate kinase catalyzes this reaction: phosphoenolpyruvate + ADP → pyruvate + ATP Calculate the equilibrium constant for this reaction from the following information. (R 8.315 J/mol K; T = 298 K) Reaction 1: ATP → ADP+ Pi AG-30.5 kJ/mol Reaction 2: AGO-61.9 kJ/mol phosphoenolpyruvate pyruvate + PiUse the following information corresponding to 1 Molar concentrations of reactants and products for Questions 1 -6. 1,3-Bisphosphoglycerate + ADP →ATP + 3-Phosphoglycerate + H+: ΔH = 41.02 kJ/mol and ΔS = 0.3030 kJ/molK. Based on the information given above, Which of the following statements regarding this folding process are correct?__ Enthalpically driven. Entropically driven. Enthalpicaly Opposed Entropically Opposed At equilibrium Exergonic for all temperatures T Endergonic for all temperatures T Exothermic EndothermicIn glycolysis, the hydrolysis of ATP to ADP is used to drive the phosphorylation of glucose (GLC): GLC+ATP <--> ADP+GLC-6-phosphat ΔG° = −17.7 kJ What is the value of Kc for this reaction at 298K?