At 298 K chlorine is only slightly soluble in water. Thus, under a pressure of 1.00 atm of Cl,(g), 1.00 L of water at equilibrium dissolves just 0.091 mol of Cl2. Cl2(g) 2 Cl,(aq) In such solutions the Cl,(aq) concentration is 0.061 M and the concentrations of Cl-(aq) and HOCI(aq) are both 0.030 M. These two additional species are formed by the equilibrium C2(aq) + H,O(e) 2 H*(aq) + Cl¯(aq) + HOCI(aq) There are no other Cl-containing species. Compute the equilibrium constants K, and K2 for the two reactions.

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At 298 K chlorine is only slightly soluble in water. Thus,
under a pressure of 1.00 atm of Cl,(g), 1.00 L of water at
equilibrium dissolves just 0.091 mol of Cl2.
Cl2(g) 2 Cl,(aq)
In such solutions the Cl,(aq) concentration is 0.061 M and
the concentrations of Cl-(aq) and HOCI(aq) are both
0.030 M. These two additional species are formed by the
equilibrium
C2(aq) + H,O(e) 2 H*(aq) + Cl¯(aq) + HOCI(aq)
There are no other Cl-containing species. Compute the
equilibrium constants K, and K2 for the two reactions.
Transcribed Image Text:At 298 K chlorine is only slightly soluble in water. Thus, under a pressure of 1.00 atm of Cl,(g), 1.00 L of water at equilibrium dissolves just 0.091 mol of Cl2. Cl2(g) 2 Cl,(aq) In such solutions the Cl,(aq) concentration is 0.061 M and the concentrations of Cl-(aq) and HOCI(aq) are both 0.030 M. These two additional species are formed by the equilibrium C2(aq) + H,O(e) 2 H*(aq) + Cl¯(aq) + HOCI(aq) There are no other Cl-containing species. Compute the equilibrium constants K, and K2 for the two reactions.
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