Assign the configuration of the chiral center in the structure below as R or S, then redraw the Fischer projection as a perspective drawing. Perspective drawing Fischer projection OH H- -Br
Assign the configuration of the chiral center in the structure below as R or S, then redraw the Fischer projection as a perspective drawing. Perspective drawing Fischer projection OH H- -Br
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Assign the configuration of the chiral center in the structure below as R or S, then redraw the Fischer projection as a perspective drawing.**
- **Fischer Projection:**
```
OH
|
H--C--Br
|
CH₃
```
- **Perspective Drawing:**
(Provided as an empty square, intended for the student to draw the perspective representation of the chiral molecule based on the Fischer projection.)
**Instructions:**
1. **Chiral Center Identification:**
- Identify the chiral center in the given Fischer projection. The central carbon atom (C) is bonded to four different groups: OH, Br, H, and CH₃.
2. **Assign Configuration (R or S):**
- Determine the priority of the groups attached to the chiral center based on atomic number: Br > OH > CH₃ > H.
- Orient the molecule in such a way that the lowest priority group (H) is positioned away from you.
- Trace the direction of priority from 1 to 3:
- If the path is clockwise, the configuration is R.
- If the path is counterclockwise, the configuration is S.
3. **Redraw as a Perspective Drawing:**
- Draw the carbon atom as a wedge-and-dash representation, showing the three-dimensional orientation.
- Use wedge lines to represent bonds coming out of the plane and dashed lines for bonds going behind the plane.
**Note:** This exercise enhances understanding of stereochemistry by translating two-dimensional Fischer projections into three-dimensional perspective drawings.
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