A→products What would be the final concentration of A after 37.3 minutes, if in this first order reaction you started with 13 M of A? The half life of A is 3,573 seconds.

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Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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### First Order Reaction Problem Statement

**Reaction:**  
A → products

**Problem:**  
What would be the final concentration of A after 37.3 minutes, if in this first-order reaction you started with 13 M of A? The half-life of A is 3,573 seconds.

**Solution Steps:**

To find the final concentration of A, we need to use the first-order kinetics formula:

\[ [A]_t = [A]_0 \times e^{-kt} \]

Where:
- \([A]_t\) is the concentration of A at time \(t\)
- \([A]_0\) is the initial concentration of A
- \(k\) is the rate constant
- \(t\) is the time

First, we need to determine the rate constant, \(k\), using the half-life of a first-order reaction:

\[ t_{1/2} = \frac{0.693}{k} \]

Given, \(t_{1/2} = 3,573\) seconds:

\[ k = \frac{0.693}{3,573 \, \text{seconds}} \]

Now, convert 37.3 minutes to seconds:

\[ 37.3 \, \text{minutes} \times 60 \, \text{seconds/minute} = 2,238 \, \text{seconds} \]

We can now substitute these values into the first-order kinetics formula to find \([A]_t\).
Transcribed Image Text:### First Order Reaction Problem Statement **Reaction:** A → products **Problem:** What would be the final concentration of A after 37.3 minutes, if in this first-order reaction you started with 13 M of A? The half-life of A is 3,573 seconds. **Solution Steps:** To find the final concentration of A, we need to use the first-order kinetics formula: \[ [A]_t = [A]_0 \times e^{-kt} \] Where: - \([A]_t\) is the concentration of A at time \(t\) - \([A]_0\) is the initial concentration of A - \(k\) is the rate constant - \(t\) is the time First, we need to determine the rate constant, \(k\), using the half-life of a first-order reaction: \[ t_{1/2} = \frac{0.693}{k} \] Given, \(t_{1/2} = 3,573\) seconds: \[ k = \frac{0.693}{3,573 \, \text{seconds}} \] Now, convert 37.3 minutes to seconds: \[ 37.3 \, \text{minutes} \times 60 \, \text{seconds/minute} = 2,238 \, \text{seconds} \] We can now substitute these values into the first-order kinetics formula to find \([A]_t\).
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