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Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Solar Chemical Energy Storage. The major ways to utilize, capture, or store the sun’s energy are solar thermal (see P8-16B), solar voltaic, biomass conversion, solar water splitting (P10-13B), and solar chemical. Solar chemical refers to processes that harness and store solar energy by adsorbing light in a reversible chemical reaction; see http://en.wikipedia.org/wiki/Solar_chemical. For example, the photodimerization of anthracene absorbs and stores solar energy that can be released when the reverse reaction takes place.Another reaction of interest is the Norbornadiene–Quadricyclane (NQ) couple, where solar energy is adsorbed and stored in one direction and released in the other.
(a) Suggest a rate law for the reversible photodimerization of anthracene.
(b) Suggest a rate law for the reversible storage of energy by the NQ couple.
(a) Suggest a rate law for the reversible photodimerization of anthracene.
(b) Suggest a rate law for the reversible storage of energy by the NQ couple.
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