and they then enter a region of uniform magnetic field. The field bends the ions into circular trajectories, but after just half a circle they either strike the wall or pass through. a small opening to a detector. As the accelerating voltage is slowly increased, different ions reach the detector and are measured. Consider a mass spectrometer with a 200.00 mT magnetic field and an 8.0000 cm spacing between the entrance and exit holes. Figure AV 1 of 1 1 u = 1.6605 x 10-27 kg, e = 1.6022 × 10-¹⁹ C. Atomic masses 12 C 14N 160 Express your answer to five significant figures and include the appropriate units. AVO;= Submit Part B 12.000 u 14.003 u 15.995 u AVN; = μA Value Request Answer What accelerating potential difference AV is required to detect N? Express your answer to five significant figures and include the appropriate units. μÀ Units Value ? C 図]? Units

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**Mass Spectrometer Analysis**

**Introduction:**
(Figure 1) illustrates a mass spectrometer, an analytical instrument used to determine the various molecules in a sample by measuring their charge-to-mass ratio \( \frac{q}{m} \). The sample is ionized, and the positive ions are accelerated from rest through a potential difference \( \Delta V \). They then enter a region of uniform magnetic field, causing the ions to bend into circular trajectories. After half a circle, they either strike the wall or pass through a small opening to a detector. By gradually increasing the accelerating voltage, different ions are detected and measured. The mass spectrometer in this example uses a 200.00 mT magnetic field and has an 8.0000 cm spacing between the entrance and exit holes.

**Diagram Explanation:**
The diagram shows a side view of the mass spectrometer setup. Ions are accelerated through a potential difference \( \Delta V \), creating a path indicated by a semicircular trajectory towards a detector. The variable spacing \( d \) denotes the distance between entrance and exit holes.

**Problem Statement:**

**Part A:**
Calculate the accelerating potential difference \( \Delta V \) required to detect the ion \( \mathrm{O}_2^+ \). The atomic masses are given as follows:

- \( ^{12}\mathrm{C} \): 12.000 u
- \( ^{14}\mathrm{N} \): 14.003 u
- \( ^{16}\mathrm{O} \): 15.995 u

Constants for calculation: 
- \( 1 \, \text{u} = 1.6605 \times 10^{-27} \, \text{kg} \)
- \( e = 1.6022 \times 10^{-19} \, \text{C} \)

Express your answer with five significant figures and include appropriate units.

\( \Delta V_{\mathrm{O}_2^+} = \) [Value] [Units]

**Part B:**
Determine the accelerating potential difference \( \Delta V \) needed to detect \( \mathrm{N}_2^+ \).

Express your answer with five significant figures and include appropriate units.

\( \Delta V_{\mathrm{N}_2^+} = \) [Value] [Units]

---

Submit your answers to obtain feedback.
Transcribed Image Text:**Mass Spectrometer Analysis** **Introduction:** (Figure 1) illustrates a mass spectrometer, an analytical instrument used to determine the various molecules in a sample by measuring their charge-to-mass ratio \( \frac{q}{m} \). The sample is ionized, and the positive ions are accelerated from rest through a potential difference \( \Delta V \). They then enter a region of uniform magnetic field, causing the ions to bend into circular trajectories. After half a circle, they either strike the wall or pass through a small opening to a detector. By gradually increasing the accelerating voltage, different ions are detected and measured. The mass spectrometer in this example uses a 200.00 mT magnetic field and has an 8.0000 cm spacing between the entrance and exit holes. **Diagram Explanation:** The diagram shows a side view of the mass spectrometer setup. Ions are accelerated through a potential difference \( \Delta V \), creating a path indicated by a semicircular trajectory towards a detector. The variable spacing \( d \) denotes the distance between entrance and exit holes. **Problem Statement:** **Part A:** Calculate the accelerating potential difference \( \Delta V \) required to detect the ion \( \mathrm{O}_2^+ \). The atomic masses are given as follows: - \( ^{12}\mathrm{C} \): 12.000 u - \( ^{14}\mathrm{N} \): 14.003 u - \( ^{16}\mathrm{O} \): 15.995 u Constants for calculation: - \( 1 \, \text{u} = 1.6605 \times 10^{-27} \, \text{kg} \) - \( e = 1.6022 \times 10^{-19} \, \text{C} \) Express your answer with five significant figures and include appropriate units. \( \Delta V_{\mathrm{O}_2^+} = \) [Value] [Units] **Part B:** Determine the accelerating potential difference \( \Delta V \) needed to detect \( \mathrm{N}_2^+ \). Express your answer with five significant figures and include appropriate units. \( \Delta V_{\mathrm{N}_2^+} = \) [Value] [Units] --- Submit your answers to obtain feedback.
## Understanding the Mass Spectrometer

### Introduction

A mass spectrometer is an analytical instrument used to identify various molecules in a sample by measuring their charge-to-mass ratio (\( q/m \)). The process begins with the ionization of the sample, where positive ions are accelerated from rest through a potential difference (\( \Delta V \)). These ions then enter a region with a uniform magnetic field, which bends their paths into circular trajectories. Ions that complete half a circular path may strike a wall or pass through an exit hole to reach a detector. Adjusting the accelerating voltage allows different ions to be detected based on their unique paths and speeds.

### Diagram Overview

The figure depicts the mass spectrometer:

- **Acceleration Region**: Ions are accelerated through a potential difference (\( \Delta V \)) as they move toward the magnetic field.
- **Magnetic Field**: Represented by blue dots, the magnetic field redirects the ions into semicircular paths.
- **Detector**: Positioned at the exit path for ions that pass through the exit hole.
- **Path**: Ionic paths are curved, and only ions with specific charge-to-mass ratios will reach the detector.

### Variables and Parameters

- **Magnetic Field Strength**: 200.00 mT
- **Distance (\( d \))**: 8.0000 cm between entrance and exit holes.

### Part B

Investigate what accelerating potential difference (\( \Delta V \)) is necessary to detect \( N_2^+ \) ions.

**Input Required:**
- Express the potential difference to five significant figures with appropriate units.

### Part C

Explore the detection of \( CO^+ \) ions, noting that \( N_2^+ \) and \( CO^+ \) have a nominal molecular mass of 28, yet are distinguished by slightly different accelerating voltages.

**Input Required:**
- Express the potential difference to five significant figures with appropriate units.

### Conclusion

Adjusting the potential difference and measuring the resulting ion paths is essential to identifying and distinguishing between ions of similar mass but different compositions in a mass spectrometer.
Transcribed Image Text:## Understanding the Mass Spectrometer ### Introduction A mass spectrometer is an analytical instrument used to identify various molecules in a sample by measuring their charge-to-mass ratio (\( q/m \)). The process begins with the ionization of the sample, where positive ions are accelerated from rest through a potential difference (\( \Delta V \)). These ions then enter a region with a uniform magnetic field, which bends their paths into circular trajectories. Ions that complete half a circular path may strike a wall or pass through an exit hole to reach a detector. Adjusting the accelerating voltage allows different ions to be detected based on their unique paths and speeds. ### Diagram Overview The figure depicts the mass spectrometer: - **Acceleration Region**: Ions are accelerated through a potential difference (\( \Delta V \)) as they move toward the magnetic field. - **Magnetic Field**: Represented by blue dots, the magnetic field redirects the ions into semicircular paths. - **Detector**: Positioned at the exit path for ions that pass through the exit hole. - **Path**: Ionic paths are curved, and only ions with specific charge-to-mass ratios will reach the detector. ### Variables and Parameters - **Magnetic Field Strength**: 200.00 mT - **Distance (\( d \))**: 8.0000 cm between entrance and exit holes. ### Part B Investigate what accelerating potential difference (\( \Delta V \)) is necessary to detect \( N_2^+ \) ions. **Input Required:** - Express the potential difference to five significant figures with appropriate units. ### Part C Explore the detection of \( CO^+ \) ions, noting that \( N_2^+ \) and \( CO^+ \) have a nominal molecular mass of 28, yet are distinguished by slightly different accelerating voltages. **Input Required:** - Express the potential difference to five significant figures with appropriate units. ### Conclusion Adjusting the potential difference and measuring the resulting ion paths is essential to identifying and distinguishing between ions of similar mass but different compositions in a mass spectrometer.
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