Ancient statues made of marble (a form of calcium carbonate) are damaged by acid rain because the reaction between the sulfuric acid in the rain and calcium carbonate produces soluble calcium sulfate, which washes away: CaCO3(s)+H₂SO4 (aq) CaSO4 (aq) + CO₂(g)+H₂O(1) Suppose an engineer decides to study the rate of this reaction. She prepares four reaction vessels by adding 162.5 g of solid calcium carbonate and 56. mL of 5.0 M sulfuric acid solution to each, and then filling the remainder of the vessel with distilled water. The volume and temperature of each vessel is shown in the table below. Arrange the reaction vessels in decreasing order of initial rate of reaction. In other words, select a "1" next to the vessel in which the engineer can reasonably expect the initial rate of reaction to be highest, a "2" next to the vessel in which the initial rate of reaction would be next highest, and so on. vessel volume temperature पह B C D 4.0 L 2.0 L 8.0 L 1.0 L 24 °C 24. C 24. °C 24 °C initial rate of reaction ? 2 ? ? v v v ✓

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Ancient statues made of marble (a form of calcium carbonate) are damaged by acid rain because the reaction between the sulfuric acid in the rain and calcium
carbonate produces soluble calcium sulfate, which washes away:
CaCO3(s)+H₂SO4 (aq)
CaSO4 (aq)+CO₂(g) +H₂O(1)
Suppose an engineer decides to study the rate of this reaction. She prepares four reaction vessels by adding 162.5 g of solid calcium carbonate and 56. mL of
5.0 M sulfuric acid solution to each, and then filling the remainder of the vessel with distilled water. The volume and temperature of each vessel is shown in the
table below.
Arrange the reaction vessels in decreasing order of initial rate of reaction. In other words, select a "1" next to the vessel in which the engineer can reasonably
expect the initial rate of reaction to be highest, a "2" next to the vessel in which the initial rate of reaction would be next highest, and so on.
vessel volume temperature
B
C
D
4.0 L
2.0 L
8.0 L
1.0 L
24 °C
→
24. °C
24. °C
24 °C
initial rate of
reaction
2
?
?
Fot
?
3
v
v
v
Transcribed Image Text:Ancient statues made of marble (a form of calcium carbonate) are damaged by acid rain because the reaction between the sulfuric acid in the rain and calcium carbonate produces soluble calcium sulfate, which washes away: CaCO3(s)+H₂SO4 (aq) CaSO4 (aq)+CO₂(g) +H₂O(1) Suppose an engineer decides to study the rate of this reaction. She prepares four reaction vessels by adding 162.5 g of solid calcium carbonate and 56. mL of 5.0 M sulfuric acid solution to each, and then filling the remainder of the vessel with distilled water. The volume and temperature of each vessel is shown in the table below. Arrange the reaction vessels in decreasing order of initial rate of reaction. In other words, select a "1" next to the vessel in which the engineer can reasonably expect the initial rate of reaction to be highest, a "2" next to the vessel in which the initial rate of reaction would be next highest, and so on. vessel volume temperature B C D 4.0 L 2.0 L 8.0 L 1.0 L 24 °C → 24. °C 24. °C 24 °C initial rate of reaction 2 ? ? Fot ? 3 v v v
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