An herbicide is found to contain only C, H, N, and Cl.The complete combustion of a 100.0-mg sample of theherbicide in excess oxygen produces 83.16 mL of CO2 and73.30 mL of H2O vapor expressed at STP. A separate analysisshows that the sample also contains 16.44 mg of Cl.(a) Determine the percentage of the composition of thesubstance. (b) Calculate its empirical formula. (c) Whatother information would you need to know about thiscompound to calculate its true molecular formula?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter5: Gases
Section: Chapter Questions
Problem 147AE: An organic compound contains C, H, N, and O. Combustion of 0.1023 g of the compound in excess oxygen...
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An herbicide is found to contain only C, H, N, and Cl.
The complete combustion of a 100.0-mg sample of the
herbicide in excess oxygen produces 83.16 mL of CO2 and
73.30 mL of H2O vapor expressed at STP. A separate analysis
shows that the sample also contains 16.44 mg of Cl.
(a) Determine the percentage of the composition of the
substance. (b) Calculate its empirical formula. (c) What
other information would you need to know about this
compound to calculate its true molecular formula?

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