An example of the McFayden-Stevens reaction is shown below, in which an acyl chloride is converted to an aldehyde. First, benzoyl chloride is reacted with hydrazine, H2NNH2, the product of which is reacted with benzenesulfonyl chloride. The result is a 1-benzoyl-2-benzenesulfonylhydrazide, which, when heated under basic conditions, decomposes into the aldehyde. Provide the detailed mechanism showing the conversion of benzoyl chloride into 1-benzoyl-2-benzenesulfonylhydrazide. H 1. H,NNH2 Na,CO3 CI `SO,C;H5 2. CgHgSO2CI A Benzoyl chloride 1-Benzoyl-2-benzenesulfonylhydrazide Benzaldehyde
An example of the McFayden-Stevens reaction is shown below, in which an acyl chloride is converted to an aldehyde. First, benzoyl chloride is reacted with hydrazine, H2NNH2, the product of which is reacted with benzenesulfonyl chloride. The result is a 1-benzoyl-2-benzenesulfonylhydrazide, which, when heated under basic conditions, decomposes into the aldehyde. Provide the detailed mechanism showing the conversion of benzoyl chloride into 1-benzoyl-2-benzenesulfonylhydrazide. H 1. H,NNH2 Na,CO3 CI `SO,C;H5 2. CgHgSO2CI A Benzoyl chloride 1-Benzoyl-2-benzenesulfonylhydrazide Benzaldehyde
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![An example of the McFayden-Stevens reaction is shown below, in which an acyl chloride is converted to an aldehyde.
First, benzoyl chloride is reacted with hydrazine, H2NNH2, the product of which is reacted with benzenesulfonyl
chloride. The result is a 1-benzoyl-2-benzenesulfonylhydrazide, which, when heated under basic conditions,
decomposes into the aldehyde. Provide the detailed mechanism showing the conversion of benzoyl chloride into
1-benzoyl-2-benzenesulfonylhydrazide.
H
1. H,NNH2
Na,CO3
CI
`SO,C;H5
2. CgHgSO2CI
A
Benzoyl chloride
1-Benzoyl-2-benzenesulfonylhydrazide
Benzaldehyde](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F936df318-5fa4-4248-b26e-169bc6f331d8%2Fc85f62a3-aeac-46db-a5cb-12bc19a0db4d%2F0eh5jmh.png&w=3840&q=75)
Transcribed Image Text:An example of the McFayden-Stevens reaction is shown below, in which an acyl chloride is converted to an aldehyde.
First, benzoyl chloride is reacted with hydrazine, H2NNH2, the product of which is reacted with benzenesulfonyl
chloride. The result is a 1-benzoyl-2-benzenesulfonylhydrazide, which, when heated under basic conditions,
decomposes into the aldehyde. Provide the detailed mechanism showing the conversion of benzoyl chloride into
1-benzoyl-2-benzenesulfonylhydrazide.
H
1. H,NNH2
Na,CO3
CI
`SO,C;H5
2. CgHgSO2CI
A
Benzoyl chloride
1-Benzoyl-2-benzenesulfonylhydrazide
Benzaldehyde
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