An example of the McFayden-Stevens reaction is shown below, in which an acyl chloride is converted to an aldehyde. First, benzoyl chloride is reacted with hydrazine, H2NNH2, the product of which is reacted with benzenesulfonyl chloride. The result is a 1-benzoyl-2-benzenesulfonylhydrazide, which, when heated under basic conditions, decomposes into the aldehyde. Provide the detailed mechanism showing the conversion of benzoyl chloride into 1-benzoyl-2-benzenesulfonylhydrazide. H 1. H,NNH2 Na,CO3 CI `SO,C;H5 2. CgHgSO2CI A Benzoyl chloride 1-Benzoyl-2-benzenesulfonylhydrazide Benzaldehyde

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An example of the McFayden-Stevens reaction is shown below, in which an acyl chloride is converted to an aldehyde.
First, benzoyl chloride is reacted with hydrazine, H2NNH2, the product of which is reacted with benzenesulfonyl
chloride. The result is a 1-benzoyl-2-benzenesulfonylhydrazide, which, when heated under basic conditions,
decomposes into the aldehyde. Provide the detailed mechanism showing the conversion of benzoyl chloride into
1-benzoyl-2-benzenesulfonylhydrazide.
H
1. H,NNH2
Na,CO3
CI
`SO,C;H5
2. CgHgSO2CI
A
Benzoyl chloride
1-Benzoyl-2-benzenesulfonylhydrazide
Benzaldehyde
Transcribed Image Text:An example of the McFayden-Stevens reaction is shown below, in which an acyl chloride is converted to an aldehyde. First, benzoyl chloride is reacted with hydrazine, H2NNH2, the product of which is reacted with benzenesulfonyl chloride. The result is a 1-benzoyl-2-benzenesulfonylhydrazide, which, when heated under basic conditions, decomposes into the aldehyde. Provide the detailed mechanism showing the conversion of benzoyl chloride into 1-benzoyl-2-benzenesulfonylhydrazide. H 1. H,NNH2 Na,CO3 CI `SO,C;H5 2. CgHgSO2CI A Benzoyl chloride 1-Benzoyl-2-benzenesulfonylhydrazide Benzaldehyde
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