An elusive intermediate of atmo spheric reactions of HONO may be nitrosyl O-hydroxide, HOON. Electronic structure calculations seem to indicate that HOON is best represented by a combination of three resonance structures, with major contribution from a radical-pair structure (involving HO and NO rad icals), significan t contribution from a molecular structure, and a small contribution from an ion-pair structure (involving HO- and NO+ ions). Use the information to represent the structure of HOON in terms of these three resonance structures.
An elusive intermediate of atmo spheric reactions of HONO may be nitrosyl O-hydroxide, HOON. Electronic structure calculations seem to indicate that HOON is best represented by a combination of three resonance structures, with major contribution from a radical-pair structure (involving HO and NO rad icals), significan t contribution from a molecular structure, and a small contribution from an ion-pair structure (involving HO- and NO+ ions). Use the information to represent the structure of HOON in terms of these three resonance structures.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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An elusive intermediate of atmo spheric reactions of HONO may be nitrosyl O-hydroxide, HOON. Electronic structure calculations seem to indicate that HOON is best represented by a combination of three resonance structures, with major contribution from a radical-pair structure (involving HO and NO rad icals), significan t contribution from a molecular structure, and a small contribution from an ion-pair structure (involving HO- and NO+ ions). Use the information to represent the structure of HOON in terms of these three resonance structures.
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