:)An aqueous mixture that contains 0.100 M Ni²+ and 0.100 M Fe3+ is titrated with a 0.100 M CO;?-. (K,= 1.0 x 10-10 for Fe (CO;);and Kp = 1.3 x 10-7 for N¡CO3) (a) Which cation precipitates first? (b) What is pCO3²- at the first and second equivalence points. (c) Can the two ions be separated with 80.00% efficiency?
:)An aqueous mixture that contains 0.100 M Ni²+ and 0.100 M Fe3+ is titrated with a 0.100 M CO;?-. (K,= 1.0 x 10-10 for Fe (CO;);and Kp = 1.3 x 10-7 for N¡CO3) (a) Which cation precipitates first? (b) What is pCO3²- at the first and second equivalence points. (c) Can the two ions be separated with 80.00% efficiency?
Chapter11: Solving Equilibrium Problems For Complex Systems
Section: Chapter Questions
Problem 11.16QAP
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