Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![### Solubility and Precipitation of Metal Hydroxides
An acidic solution is 9 mM in each of the following metal ions: \( \text{Sn}^{2+}, \text{Co}^{2+}, \text{Mn}^{2+}, \text{Pb}^{2+} \). View the Solubility Product Constant Table provided.
**(a) At what pH do the metal hydroxides begin to precipitate?**
- \( \text{Sn(OH)}_2: \) pH 1.89
- \( \text{Co(OH)}_2: \) pH 7.9
- \( \text{Mn(OH)}_2: \) pH 8.4
- \( \text{Pb(OH)}_2: \) pH 5.1
**Substance** | **\( K_{sp} \) at 25 °C**
--- | ---
**Aluminum**
\( \text{Al(OH)}_3 \) | \( 1.9 \times 10^{-33} \)
**Barium**
\( \text{Ba(OH)}_2 \) | \( 5.0 \times 10^{-3} \)
\( \text{BaCO}_3 \) | \( 8.1 \times 10^{-9} \)
\( \text{BaSO}_4 \) | \( 1.1 \times 10^{-10} \)
**Cadmium**
\( \text{Cd(OH)}_2 \) | \( 2.5 \times 10^{-14} \)
\( \text{CdCO}_3 \) | \( 5.2 \times 10^{-12} \)
**Calcium**
\( \text{Ca(OH)}_2 \) | \( 5.5 \times 10^{-6} \)
\( \text{CaCO}_3 \) | \( 3.8 \times 10^{-9} \)
\( \text{CaF}_2 \) | \( 3.9 \times 10^{-11} \)
**Chromium**
\( \text{Cr(OH)}_3 \) | \( 6.3 \times 10^{-31} \)
**Cobalt**
\( \text{Co(OH)}_2 \](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F61ff295b-afd4-43c3-8ed2-2cc17b9c2249%2F3b5a00eb-e31f-49f5-b00b-614c9eafca2e%2Fq2v82f_processed.png&w=3840&q=75)
Transcribed Image Text:### Solubility and Precipitation of Metal Hydroxides
An acidic solution is 9 mM in each of the following metal ions: \( \text{Sn}^{2+}, \text{Co}^{2+}, \text{Mn}^{2+}, \text{Pb}^{2+} \). View the Solubility Product Constant Table provided.
**(a) At what pH do the metal hydroxides begin to precipitate?**
- \( \text{Sn(OH)}_2: \) pH 1.89
- \( \text{Co(OH)}_2: \) pH 7.9
- \( \text{Mn(OH)}_2: \) pH 8.4
- \( \text{Pb(OH)}_2: \) pH 5.1
**Substance** | **\( K_{sp} \) at 25 °C**
--- | ---
**Aluminum**
\( \text{Al(OH)}_3 \) | \( 1.9 \times 10^{-33} \)
**Barium**
\( \text{Ba(OH)}_2 \) | \( 5.0 \times 10^{-3} \)
\( \text{BaCO}_3 \) | \( 8.1 \times 10^{-9} \)
\( \text{BaSO}_4 \) | \( 1.1 \times 10^{-10} \)
**Cadmium**
\( \text{Cd(OH)}_2 \) | \( 2.5 \times 10^{-14} \)
\( \text{CdCO}_3 \) | \( 5.2 \times 10^{-12} \)
**Calcium**
\( \text{Ca(OH)}_2 \) | \( 5.5 \times 10^{-6} \)
\( \text{CaCO}_3 \) | \( 3.8 \times 10^{-9} \)
\( \text{CaF}_2 \) | \( 3.9 \times 10^{-11} \)
**Chromium**
\( \text{Cr(OH)}_3 \) | \( 6.3 \times 10^{-31} \)
**Cobalt**
\( \text{Co(OH)}_2 \
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