Among the solubility rules previously discussed is the statement: Carbonates, phosphates, borates, and arsenates—except those of the ammonium ion and the alkali metals—are insoluble.(a) Write the expression for the equilibrium constant for the reaction represented by the equationCaCO3(s) ⇌ Ca2+(aq) + CO32−(aq).Is Kc> 1, < 1, or ≈ 1? Explain your answer. (b) Write the expression for the equilibrium constant for the reaction represented by the equation3Ba2+(aq) + 2PO43−(aq) ⇌ Ba3⎛⎝PO4⎞⎠2(s).Is Kc> 1, < 1, or ≈ 1? Explain your answer

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter16: Solubility And Precipitation Equilibria
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Among the solubility rules previously discussed is the statement: Carbonates, phosphates, borates, and arsenates—except those of the ammonium ion and the alkali metals—are insoluble.(a) Write the expression for the equilibrium constant for the reaction represented by the equationCaCO3(s) ⇌ Ca2+(aq) + CO32−(aq).Is Kc> 1, < 1, or ≈ 1? Explain your answer. (b) Write the expression for the equilibrium constant for the reaction represented by the equation3Ba2+(aq) + 2PO43−(aq) ⇌ Ba3⎛⎝PO4⎞⎠2(s).Is Kc> 1, < 1, or ≈ 1? Explain your answer

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